The iron-mediated intramolecular addition of carboxylates to conjugated dienes

Ming Chang P. Yeh; Li Wen Chuang; Ya Sheng Hsieh; Ming Shan Tsai

doi:10.1039/a901628g

The iron-mediated intramolecular addition of carboxylates to conjugated dienes

Ming Chang P. Yeh^*, Li Wen Chuang, Ya Sheng Hsieh, Ming Shan Tsai

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

Treatment of carboxylic acid functionalized (η⁴-diene)Fe(CO)₃ complexes with 3.0 equiv. of NOBF₄ in the presence of Et₃N generates γ- and δ-lactones containing an α,β-unsaturated aldehyde or oxime functionality after NO⁺ insertion.

Original language	English
Pages (from-to)	805-806
Number of pages	2
Journal	Chemical Communications
Issue number	9
DOIs	https://doi.org/10.1039/a901628g
Publication status	Published - 1999 May 7

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/a901628g

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title = "The iron-mediated intramolecular addition of carboxylates to conjugated dienes",

abstract = "Treatment of carboxylic acid functionalized (η4-diene)Fe(CO)3 complexes with 3.0 equiv. of NOBF4 in the presence of Et3N generates γ- and δ-lactones containing an α,β-unsaturated aldehyde or oxime functionality after NO+ insertion.",

author = "Yeh, {Ming Chang P.} and Chuang, {Li Wen} and Hsieh, {Ya Sheng} and Tsai, {Ming Shan}",

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AU - Yeh, Ming Chang P.

AU - Chuang, Li Wen

AU - Hsieh, Ya Sheng

AU - Tsai, Ming Shan

PY - 1999/5/7

Y1 - 1999/5/7

N2 - Treatment of carboxylic acid functionalized (η4-diene)Fe(CO)3 complexes with 3.0 equiv. of NOBF4 in the presence of Et3N generates γ- and δ-lactones containing an α,β-unsaturated aldehyde or oxime functionality after NO+ insertion.

AB - Treatment of carboxylic acid functionalized (η4-diene)Fe(CO)3 complexes with 3.0 equiv. of NOBF4 in the presence of Et3N generates γ- and δ-lactones containing an α,β-unsaturated aldehyde or oxime functionality after NO+ insertion.

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DO - 10.1039/a901628g

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The iron-mediated intramolecular addition of carboxylates to conjugated dienes

Abstract

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CCDC 121466: Experimental Crystal Structure Determination

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The iron-mediated intramolecular addition of carboxylates to conjugated dienes

Abstract

ASJC Scopus subject areas

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Datasets

CCDC 121466: Experimental Crystal Structure Determination

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