The influence of UV filter and Al/Ag moisture barrier layer on the outdoor stability of polymer solar cells

Chia Ning Weng, Hao Chun Yang, Cheng Yu Tsai, Szu Han Chen, Yan Syun Chen, Chao Hsuan Chen, Kuan Min Huang, Hsin Fei Meng*, Yu Chiang Chao, Chih Yu Chang, Hsiao Wen Zan, Sheng Fu Horng, Pei Chen Yu, Kuan Wei Su

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

12 Citations (Scopus)


The degradation of the polymer solar cells in the outdoor condition was studied. It was found that the devices with normal structure (ITO/PEDOT:PSS/PBDTTT-EFT:PC71BM/ZrOx/Al) show better stability than those with inverted device structure (ITO/ZnO/PBDTTT-EFT:PC71BM/MoO3/Ag). PBDTTT-EFT is poly[4, 8-bis(5-(2-ethylhexyl) thiophen-2-yl) benzo [1,2-b;4,5-b'] dithiophene-2, 6-diyl-alt-(4-(2-ethylhexyl)-3-fluorothieno [3,4-b]thiophene-) −2-carboxylate-2-6-diyl)] and PC71BM is [6,6]-phenyl-C71-butyric acid methyl ester. The major cause of degradation was attributed to the ultraviolet (UV) part of the sunlight. When the UV filter with cut-off wavelength of 400 nm was used to protect the device, the decay rate was improved by 50 times and the protected device retains 95% of their initial power conversion efficiency after 13 days outside. In the meanwhile, the decay of device fabricated by toluene was found 8 times faster than device by chlorobenzene. Thin 20 nm of Ag capping layer can further improve the stability. Degradation under water immersion indicates that the major effect of Ag is to protect against the residual moisture inside the encapsulation.

Original languageEnglish
Pages (from-to)308-316
Number of pages9
JournalSolar Energy
Publication statusPublished - 2020 Mar 15


  • Moisture barrier
  • Polymer solar cell
  • Solution-processable
  • Ultraviolet stability

ASJC Scopus subject areas

  • Renewable Energy, Sustainability and the Environment
  • General Materials Science


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