The effect of lanthanum (La) incorporation in ultra-thin ZrO2 high-κ gate dielectrics

Chuan-Hsi Liu, Pi Chun Juan, Yi Hsien Chou, Hung Wen Hsu

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Metal-oxide-semiconductor (MOS) capacitors with La-incorporated ZrO 2 (ZrLaO) high-κ gate dielectrics through co-sputtering technique have been fabricated. The effect of La incorporation on the thermal stability and electrical characteristics has been investigated. XRD spectra and HRTEM images indicate that the addition of La into ZrO2 can significantly increase the crystallization temperature of the films and inhibit the formation of interfacial layers. The technique of combined method of ellipsometer and XRR confirms that the interfacial layer is dramatically reduced with La incorporation, and the interfacial layer is identified as silicate formation through XPS depth profile. In addition, current-voltage and capacitance-voltage characteristics reveal that the relative dielectric constant and flatband voltage shift of MOS with ZrLaO dielectrics are improved with a slight reduction in barrier height.

Original languageEnglish
Pages (from-to)2-5
Number of pages4
JournalMicroelectronic Engineering
Volume89
Issue number1
DOIs
Publication statusPublished - 2012 Jan 1

Fingerprint

Lanthanum
Gate dielectrics
lanthanum
metal oxide semiconductors
Electric potential
Metals
Silicates
ellipsometers
capacitance-voltage characteristics
electric potential
Crystallization
Sputtering
silicates
capacitors
Thermodynamic stability
Capacitors
Permittivity
thermal stability
Capacitance
X ray photoelectron spectroscopy

Keywords

  • Flatband voltage shift
  • High-κ dielectrics
  • Interfacial layer
  • Thermal stability
  • XPS depth profile
  • ZrLaO

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Atomic and Molecular Physics, and Optics
  • Condensed Matter Physics
  • Surfaces, Coatings and Films
  • Electrical and Electronic Engineering

Cite this

The effect of lanthanum (La) incorporation in ultra-thin ZrO2 high-κ gate dielectrics. / Liu, Chuan-Hsi; Juan, Pi Chun; Chou, Yi Hsien; Hsu, Hung Wen.

In: Microelectronic Engineering, Vol. 89, No. 1, 01.01.2012, p. 2-5.

Research output: Contribution to journalArticle

Liu, Chuan-Hsi ; Juan, Pi Chun ; Chou, Yi Hsien ; Hsu, Hung Wen. / The effect of lanthanum (La) incorporation in ultra-thin ZrO2 high-κ gate dielectrics. In: Microelectronic Engineering. 2012 ; Vol. 89, No. 1. pp. 2-5.
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