The Compton profiles of vanadium oxides

Chu Nan Chang; Chuhn Chuh Chen; Huey Fen Liu

doi:10.1088/0953-8984/4/50/032

The Compton profiles of vanadium oxides

Chu Nan Chang^*, Chuhn Chuh Chen, Huey Fen Liu

^*Corresponding author for this work

Department of Physics

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

The isotropic Compton profiles of vanadium oxides VO, V₂O ₃, VO₂, V₆O₁₃ and V ₂O₅ were measured by using 59.54 keV gamma -rays. The Compton profiles calculated by using the molecular-cluster model were found to be improper in describing the experimental results of VO and VO₂. The molecular-cluster model seems to underestimate the metal-ligand covalency. The localization and delocalization of valence electrons when forming oxides will be discussed on the basis of the atomic superposition model.

Original language	English
Article number	032
Pages (from-to)	10445-10452
Number of pages	8
Journal	Journal of Physics: Condensed Matter
Volume	4
Issue number	50
DOIs	https://doi.org/10.1088/0953-8984/4/50/032
Publication status	Published - 1992

ASJC Scopus subject areas

General Materials Science
Condensed Matter Physics

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10.1088/0953-8984/4/50/032

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title = "The Compton profiles of vanadium oxides",

abstract = "The isotropic Compton profiles of vanadium oxides VO, V2O 3, VO2, V6O13 and V 2O5 were measured by using 59.54 keV gamma -rays. The Compton profiles calculated by using the molecular-cluster model were found to be improper in describing the experimental results of VO and VO2. The molecular-cluster model seems to underestimate the metal-ligand covalency. The localization and delocalization of valence electrons when forming oxides will be discussed on the basis of the atomic superposition model.",

author = "Chang, {Chu Nan} and Chen, {Chuhn Chuh} and Liu, {Huey Fen}",

year = "1992",

doi = "10.1088/0953-8984/4/50/032",

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AU - Chang, Chu Nan

AU - Chen, Chuhn Chuh

AU - Liu, Huey Fen

PY - 1992

Y1 - 1992

N2 - The isotropic Compton profiles of vanadium oxides VO, V2O 3, VO2, V6O13 and V 2O5 were measured by using 59.54 keV gamma -rays. The Compton profiles calculated by using the molecular-cluster model were found to be improper in describing the experimental results of VO and VO2. The molecular-cluster model seems to underestimate the metal-ligand covalency. The localization and delocalization of valence electrons when forming oxides will be discussed on the basis of the atomic superposition model.

AB - The isotropic Compton profiles of vanadium oxides VO, V2O 3, VO2, V6O13 and V 2O5 were measured by using 59.54 keV gamma -rays. The Compton profiles calculated by using the molecular-cluster model were found to be improper in describing the experimental results of VO and VO2. The molecular-cluster model seems to underestimate the metal-ligand covalency. The localization and delocalization of valence electrons when forming oxides will be discussed on the basis of the atomic superposition model.

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DO - 10.1088/0953-8984/4/50/032

M3 - Article

AN - SCOPUS:33645903039

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JO - Journal of Physics: Condensed Matter

JF - Journal of Physics: Condensed Matter

IS - 50

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ER -

The Compton profiles of vanadium oxides

Abstract

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