The Addition of the Highly Functionalized Zinc, Copper Reagents RCu(CN)ZnI to Nitro Olefins

Carole Retherford; Ming Chang P. Yeh; Ioana Schipor; Huai Gu Chen; Paul Knochel

doi:10.1021/jo00283a005

The Addition of the Highly Functionalized Zinc, Copper Reagents RCu(CN)ZnI to Nitro Olefins

Carole Retherford, Ming Chang P. Yeh, Ioana Schipor, Huai Gu Chen, Paul Knochel^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

34 Citations (Scopus)

Abstract

: The addition of the highly functionalized zinc and copper organometallics FG-RCu(CN)ZnI to nitro olefins furnishes polyfunctional nitroalkanes in good to excellent yields; with α-substituted nitro olefins, the Michael adducts can be directly converted into polyfunctional ketones.

Original language	English
Pages (from-to)	5200-5202
Number of pages	3
Journal	Journal of Organic Chemistry
Volume	54
Issue number	22
DOIs	https://doi.org/10.1021/jo00283a005
Publication status	Published - 1989 Oct 1
Externally published	Yes

ASJC Scopus subject areas

Organic Chemistry

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10.1021/jo00283a005

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title = "The Addition of the Highly Functionalized Zinc, Copper Reagents RCu(CN)ZnI to Nitro Olefins",

abstract = ": The addition of the highly functionalized zinc and copper organometallics FG-RCu(CN)ZnI to nitro olefins furnishes polyfunctional nitroalkanes in good to excellent yields; with α-substituted nitro olefins, the Michael adducts can be directly converted into polyfunctional ketones.",

author = "Carole Retherford and Yeh, {Ming Chang P.} and Ioana Schipor and Chen, {Huai Gu} and Paul Knochel",

year = "1989",

month = oct,

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doi = "10.1021/jo00283a005",

language = "English",

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journal = "Journal of Organic Chemistry",

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T1 - The Addition of the Highly Functionalized Zinc, Copper Reagents RCu(CN)ZnI to Nitro Olefins

AU - Retherford, Carole

AU - Yeh, Ming Chang P.

AU - Schipor, Ioana

AU - Chen, Huai Gu

AU - Knochel, Paul

PY - 1989/10/1

Y1 - 1989/10/1

N2 - : The addition of the highly functionalized zinc and copper organometallics FG-RCu(CN)ZnI to nitro olefins furnishes polyfunctional nitroalkanes in good to excellent yields; with α-substituted nitro olefins, the Michael adducts can be directly converted into polyfunctional ketones.

AB - : The addition of the highly functionalized zinc and copper organometallics FG-RCu(CN)ZnI to nitro olefins furnishes polyfunctional nitroalkanes in good to excellent yields; with α-substituted nitro olefins, the Michael adducts can be directly converted into polyfunctional ketones.

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DO - 10.1021/jo00283a005

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The Addition of the Highly Functionalized Zinc, Copper Reagents RCu(CN)ZnI to Nitro Olefins

Abstract

ASJC Scopus subject areas

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