Synthesis, structures, properties, and chemical-sensor application of iridium(III) bis-cyclometallated complexes with two pyridine-derived ligands

Wu Sian Sie, Gene Hsiang Lee, Kevin Yun Da Tsai, I. Jy Chang, Kom Bei Shiu

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

Treatment of cis-[Ir(η2-ppy)2(MeCN)2]NO3 (1, ppy = 2-phenylpyridine) with isonicotinaldehyde, ethyl isonicotinate, and 4-aminopyridine afforded cis-[Ir(η2-ppy)2L2]NO3 (L = 4-pyCHO (2), 4-pyCOOEt (3), 4-pyNH2 (4)). The photophysical properties of these complexes were determined. Complex 4 is a good light-emitting chemical sensor toward silver trifluoromethanesulfonate in methanol. Crystal structures of 2 and 3 as well as that of the adduct, formed between 4 and AgNO3, have been characterized by X-ray diffraction.

Original languageEnglish
Pages (from-to)198-202
Number of pages5
JournalJournal of Molecular Structure
Volume890
Issue number1-3
DOIs
Publication statusPublished - 2008 Nov 12

Fingerprint

Iridium
4-Aminopyridine
Chemical sensors
Methanol
Crystal structure
Ligands
X ray diffraction
pyridine
trifluoromethanesulfonic acid
2-phenylpyridine
ethyl isonicotinate

Keywords

  • Cyclometallated complexes
  • Iridium(III)
  • Sensor

ASJC Scopus subject areas

  • Analytical Chemistry
  • Spectroscopy
  • Organic Chemistry
  • Inorganic Chemistry

Cite this

Synthesis, structures, properties, and chemical-sensor application of iridium(III) bis-cyclometallated complexes with two pyridine-derived ligands. / Sie, Wu Sian; Lee, Gene Hsiang; Tsai, Kevin Yun Da; Chang, I. Jy; Shiu, Kom Bei.

In: Journal of Molecular Structure, Vol. 890, No. 1-3, 12.11.2008, p. 198-202.

Research output: Contribution to journalArticle

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AU - Chang, I. Jy

AU - Shiu, Kom Bei

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N2 - Treatment of cis-[Ir(η2-ppy)2(MeCN)2]NO3 (1, ppy = 2-phenylpyridine) with isonicotinaldehyde, ethyl isonicotinate, and 4-aminopyridine afforded cis-[Ir(η2-ppy)2L2]NO3 (L = 4-pyCHO (2), 4-pyCOOEt (3), 4-pyNH2 (4)). The photophysical properties of these complexes were determined. Complex 4 is a good light-emitting chemical sensor toward silver trifluoromethanesulfonate in methanol. Crystal structures of 2 and 3 as well as that of the adduct, formed between 4 and AgNO3, have been characterized by X-ray diffraction.

AB - Treatment of cis-[Ir(η2-ppy)2(MeCN)2]NO3 (1, ppy = 2-phenylpyridine) with isonicotinaldehyde, ethyl isonicotinate, and 4-aminopyridine afforded cis-[Ir(η2-ppy)2L2]NO3 (L = 4-pyCHO (2), 4-pyCOOEt (3), 4-pyNH2 (4)). The photophysical properties of these complexes were determined. Complex 4 is a good light-emitting chemical sensor toward silver trifluoromethanesulfonate in methanol. Crystal structures of 2 and 3 as well as that of the adduct, formed between 4 and AgNO3, have been characterized by X-ray diffraction.

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