Synthesis of Tellurabenziporphyrin and Its Pd(II) Complex

Sunit Kumar, Way Zen Lee, Mangalampalli Ravikanth

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

An unprecedented tellurabenziporphyrin containing C, N, and Te donor atoms was synthesized by condensing benzitripyrrane and tellurophene diol under acid catalyzed conditions. The tellurabenziporphyrin readily forms a Pd(II) complex when treated with PdCl2 in CHCl3/CH3CN. The crystal structures of tellurabenziporphyrin and its Pd(II) complex revealed that the benzene ring hinders the π-electron delocalization. An unusual five-membered ring formed inside the macrocycle due to the strong interaction between "Te" and "N" in the Pd(II) complex.

Original languageEnglish
Pages (from-to)636-639
Number of pages4
JournalOrganic Letters
Volume20
Issue number3
DOIs
Publication statusPublished - 2018 Feb 2

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Benzene
Crystal structure
Electrons
Atoms
Acids
condensing
rings
synthesis
benzene
acids
crystal structure
atoms
electrons
palladium chloride

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

Cite this

Synthesis of Tellurabenziporphyrin and Its Pd(II) Complex. / Kumar, Sunit; Lee, Way Zen; Ravikanth, Mangalampalli.

In: Organic Letters, Vol. 20, No. 3, 02.02.2018, p. 636-639.

Research output: Contribution to journalArticle

Kumar, Sunit ; Lee, Way Zen ; Ravikanth, Mangalampalli. / Synthesis of Tellurabenziporphyrin and Its Pd(II) Complex. In: Organic Letters. 2018 ; Vol. 20, No. 3. pp. 636-639.
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