Synthesis of Perinaphthenones via BF3.Et2O Mediated One-Pot Cascade 4,5-Annulation Reactions of 1-Naphthols and Ynones

Chun Wei Kuo, Naidu Sambasiva Rao, Prakash Bhimrao Patil, Ting Ta Chiang, Veerababurao Kavala, Ching Fa Yao*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

C4-C5 periannulation of 1-naphthols and ynones via BF3.Et2O mediated one-pot cascade under metal and solvent-free conditions have been developed for the synthesis of perinaphthenones. Furthermore, this strategy features the formation of new periannulation at C4-C5 positions of α-naphthol, synthesis of highly substituted perinaphthenones, broad substrate scope, readily available starting materials and good to moderate yields. The perinaphthenones products synthesized here have exhibited interesting photo physical properties. (Figure presented.).

Original languageEnglish
Pages (from-to)1935-1943
Number of pages9
JournalAdvanced Synthesis and Catalysis
Volume363
Issue number7
DOIs
Publication statusPublished - 2021 Mar 29

Keywords

  • Periannulation
  • Perinaphthenones
  • Solvent-Free
  • Ynones
  • α-naphthol

ASJC Scopus subject areas

  • Catalysis
  • Organic Chemistry

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