Synthesis of mixed ligand and pillared paddlewheel MOFs using waste polyethylene terephthalate material as sustainable ligand source

Duraisamy Senthil Raja; Chih Chiung Pan; Chia Wei Chen; Yu Hao Kang; Jiun Jen Chen; Chia Her Lin

doi:10.1016/j.micromeso.2016.05.035

Synthesis of mixed ligand and pillared paddlewheel MOFs using waste polyethylene terephthalate material as sustainable ligand source

Duraisamy Senthil Raja
, Chih Chiung Pan
, Chia Wei Chen
, Yu Hao Kang
, Jiun Jen Chen^*
, Chia Her Lin

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

A series of five isostructural pillared-paddlewheel MOFs, [M₂(BDC)₂(DABCO)] (1-5), (where M = Fe(II) (1), Co(II) (2), Ni(II) (3), Cu(II) (4) and Zn(II) (5); BDC = benzene-1,4-dicarboxylate; and DABCO = 1,4-diazabicyclo[2.2.2]octane) have been synthesized by using waste polyethylene terephthalate (PET) material as a direct BDC source. The optimal reaction condition has been achieved for all the MOFs with 100% depolymerization of waste PET material in the reaction. The synthesized MOFs have been characterized using powder X-ray diffraction, scanning electron microscopy, thermal gravimetric analyses, and N₂ gas sorption measurements. Results showed that the porous MOFs have similar properties of their corresponding literature reports.

Original language	English
Pages (from-to)	186-191
Number of pages	6
Journal	Microporous and Mesoporous Materials
Volume	231
DOIs	https://doi.org/10.1016/j.micromeso.2016.05.035
Publication status	Published - 2016 Sept 1
Externally published	Yes

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

DABCO
Metal-organic framework
Microporous material
Renewable resources
Solvothermal synthesis

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics
Mechanics of Materials

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10.1016/j.micromeso.2016.05.035

Cite this

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title = "Synthesis of mixed ligand and pillared paddlewheel MOFs using waste polyethylene terephthalate material as sustainable ligand source",

abstract = "A series of five isostructural pillared-paddlewheel MOFs, [M2(BDC)2(DABCO)] (1-5), (where M = Fe(II) (1), Co(II) (2), Ni(II) (3), Cu(II) (4) and Zn(II) (5); BDC = benzene-1,4-dicarboxylate; and DABCO = 1,4-diazabicyclo[2.2.2]octane) have been synthesized by using waste polyethylene terephthalate (PET) material as a direct BDC source. The optimal reaction condition has been achieved for all the MOFs with 100\% depolymerization of waste PET material in the reaction. The synthesized MOFs have been characterized using powder X-ray diffraction, scanning electron microscopy, thermal gravimetric analyses, and N2 gas sorption measurements. Results showed that the porous MOFs have similar properties of their corresponding literature reports.",

keywords = "DABCO, Metal-organic framework, Microporous material, Renewable resources, Solvothermal synthesis",

author = "\{Senthil Raja\}, Duraisamy and Pan, \{Chih Chiung\} and Chen, \{Chia Wei\} and Kang, \{Yu Hao\} and Chen, \{Jiun Jen\} and Lin, \{Chia Her\}",

year = "2016",

month = sep,

day = "1",

doi = "10.1016/j.micromeso.2016.05.035",

language = "English",

volume = "231",

pages = "186--191",

journal = "Microporous and Mesoporous Materials",

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TY - JOUR

T1 - Synthesis of mixed ligand and pillared paddlewheel MOFs using waste polyethylene terephthalate material as sustainable ligand source

AU - Senthil Raja, Duraisamy

AU - Pan, Chih Chiung

AU - Chen, Chia Wei

AU - Kang, Yu Hao

AU - Chen, Jiun Jen

AU - Lin, Chia Her

PY - 2016/9/1

Y1 - 2016/9/1

N2 - A series of five isostructural pillared-paddlewheel MOFs, [M2(BDC)2(DABCO)] (1-5), (where M = Fe(II) (1), Co(II) (2), Ni(II) (3), Cu(II) (4) and Zn(II) (5); BDC = benzene-1,4-dicarboxylate; and DABCO = 1,4-diazabicyclo[2.2.2]octane) have been synthesized by using waste polyethylene terephthalate (PET) material as a direct BDC source. The optimal reaction condition has been achieved for all the MOFs with 100% depolymerization of waste PET material in the reaction. The synthesized MOFs have been characterized using powder X-ray diffraction, scanning electron microscopy, thermal gravimetric analyses, and N2 gas sorption measurements. Results showed that the porous MOFs have similar properties of their corresponding literature reports.

AB - A series of five isostructural pillared-paddlewheel MOFs, [M2(BDC)2(DABCO)] (1-5), (where M = Fe(II) (1), Co(II) (2), Ni(II) (3), Cu(II) (4) and Zn(II) (5); BDC = benzene-1,4-dicarboxylate; and DABCO = 1,4-diazabicyclo[2.2.2]octane) have been synthesized by using waste polyethylene terephthalate (PET) material as a direct BDC source. The optimal reaction condition has been achieved for all the MOFs with 100% depolymerization of waste PET material in the reaction. The synthesized MOFs have been characterized using powder X-ray diffraction, scanning electron microscopy, thermal gravimetric analyses, and N2 gas sorption measurements. Results showed that the porous MOFs have similar properties of their corresponding literature reports.

KW - DABCO

KW - Metal-organic framework

KW - Microporous material

KW - Renewable resources

KW - Solvothermal synthesis

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UR - https://www.scopus.com/pages/publications/84975090397#tab=citedBy

U2 - 10.1016/j.micromeso.2016.05.035

DO - 10.1016/j.micromeso.2016.05.035

M3 - Article

AN - SCOPUS:84975090397

SN - 1387-1811

VL - 231

SP - 186

EP - 191

JO - Microporous and Mesoporous Materials

JF - Microporous and Mesoporous Materials

ER -

Synthesis of mixed ligand and pillared paddlewheel MOFs using waste polyethylene terephthalate material as sustainable ligand source

Abstract

UN SDGs

Keywords

ASJC Scopus subject areas

Access to Document

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