Synthesis of mixed ligand and pillared paddlewheel MOFs using waste polyethylene terephthalate material as sustainable ligand source

Duraisamy Senthil Raja; Chih Chiung Pan; Chia Wei Chen; Yu Hao Kang; Jiun Jen Chen; Chia Her Lin

doi:10.1016/j.micromeso.2016.05.035

Synthesis of mixed ligand and pillared paddlewheel MOFs using waste polyethylene terephthalate material as sustainable ligand source

Duraisamy Senthil Raja, Chih Chiung Pan, Chia Wei Chen, Yu Hao Kang, Jiun Jen Chen^*, Chia Her Lin

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

A series of five isostructural pillared-paddlewheel MOFs, [M₂(BDC)₂(DABCO)] (1-5), (where M = Fe(II) (1), Co(II) (2), Ni(II) (3), Cu(II) (4) and Zn(II) (5); BDC = benzene-1,4-dicarboxylate; and DABCO = 1,4-diazabicyclo[2.2.2]octane) have been synthesized by using waste polyethylene terephthalate (PET) material as a direct BDC source. The optimal reaction condition has been achieved for all the MOFs with 100% depolymerization of waste PET material in the reaction. The synthesized MOFs have been characterized using powder X-ray diffraction, scanning electron microscopy, thermal gravimetric analyses, and N₂ gas sorption measurements. Results showed that the porous MOFs have similar properties of their corresponding literature reports.

Original language	English
Pages (from-to)	186-191
Number of pages	6
Journal	Microporous and Mesoporous Materials
Volume	231
DOIs	https://doi.org/10.1016/j.micromeso.2016.05.035
Publication status	Published - 2016 Sept 1
Externally published	Yes

Keywords

DABCO
Metal-organic framework
Microporous material
Renewable resources
Solvothermal synthesis

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics
Mechanics of Materials

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.micromeso.2016.05.035

Cite this

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title = "Synthesis of mixed ligand and pillared paddlewheel MOFs using waste polyethylene terephthalate material as sustainable ligand source",

abstract = "A series of five isostructural pillared-paddlewheel MOFs, [M2(BDC)2(DABCO)] (1-5), (where M = Fe(II) (1), Co(II) (2), Ni(II) (3), Cu(II) (4) and Zn(II) (5); BDC = benzene-1,4-dicarboxylate; and DABCO = 1,4-diazabicyclo[2.2.2]octane) have been synthesized by using waste polyethylene terephthalate (PET) material as a direct BDC source. The optimal reaction condition has been achieved for all the MOFs with 100% depolymerization of waste PET material in the reaction. The synthesized MOFs have been characterized using powder X-ray diffraction, scanning electron microscopy, thermal gravimetric analyses, and N2 gas sorption measurements. Results showed that the porous MOFs have similar properties of their corresponding literature reports.",

keywords = "DABCO, Metal-organic framework, Microporous material, Renewable resources, Solvothermal synthesis",

author = "{Senthil Raja}, Duraisamy and Pan, {Chih Chiung} and Chen, {Chia Wei} and Kang, {Yu Hao} and Chen, {Jiun Jen} and Lin, {Chia Her}",

year = "2016",

month = sep,

day = "1",

doi = "10.1016/j.micromeso.2016.05.035",

language = "English",

volume = "231",

pages = "186--191",

journal = "Microporous and Mesoporous Materials",

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TY - JOUR

T1 - Synthesis of mixed ligand and pillared paddlewheel MOFs using waste polyethylene terephthalate material as sustainable ligand source

AU - Senthil Raja, Duraisamy

AU - Pan, Chih Chiung

AU - Chen, Chia Wei

AU - Kang, Yu Hao

AU - Chen, Jiun Jen

AU - Lin, Chia Her

PY - 2016/9/1

Y1 - 2016/9/1

N2 - A series of five isostructural pillared-paddlewheel MOFs, [M2(BDC)2(DABCO)] (1-5), (where M = Fe(II) (1), Co(II) (2), Ni(II) (3), Cu(II) (4) and Zn(II) (5); BDC = benzene-1,4-dicarboxylate; and DABCO = 1,4-diazabicyclo[2.2.2]octane) have been synthesized by using waste polyethylene terephthalate (PET) material as a direct BDC source. The optimal reaction condition has been achieved for all the MOFs with 100% depolymerization of waste PET material in the reaction. The synthesized MOFs have been characterized using powder X-ray diffraction, scanning electron microscopy, thermal gravimetric analyses, and N2 gas sorption measurements. Results showed that the porous MOFs have similar properties of their corresponding literature reports.

AB - A series of five isostructural pillared-paddlewheel MOFs, [M2(BDC)2(DABCO)] (1-5), (where M = Fe(II) (1), Co(II) (2), Ni(II) (3), Cu(II) (4) and Zn(II) (5); BDC = benzene-1,4-dicarboxylate; and DABCO = 1,4-diazabicyclo[2.2.2]octane) have been synthesized by using waste polyethylene terephthalate (PET) material as a direct BDC source. The optimal reaction condition has been achieved for all the MOFs with 100% depolymerization of waste PET material in the reaction. The synthesized MOFs have been characterized using powder X-ray diffraction, scanning electron microscopy, thermal gravimetric analyses, and N2 gas sorption measurements. Results showed that the porous MOFs have similar properties of their corresponding literature reports.

KW - DABCO

KW - Metal-organic framework

KW - Microporous material

KW - Renewable resources

KW - Solvothermal synthesis

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U2 - 10.1016/j.micromeso.2016.05.035

DO - 10.1016/j.micromeso.2016.05.035

M3 - Article

AN - SCOPUS:84975090397

SN - 1387-1811

VL - 231

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EP - 191

JO - Microporous and Mesoporous Materials

JF - Microporous and Mesoporous Materials

ER -

Synthesis of mixed ligand and pillared paddlewheel MOFs using waste polyethylene terephthalate material as sustainable ligand source

Abstract

Keywords

ASJC Scopus subject areas

UN SDGs

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