Abstract
An efficient, one-pot method for the synthesis of dibenzodiazepinone derivatives involving copper-catalyzed tandem C-N bond formation is reported. The use of various halo amide and 2-iodoaniline derivatives permitted the synthesis of an array of dibenzodiazepinone derivatives in moderate to good yields. Moreover, a dibenzodiazepinone derivative {2-(11-oxo-5H-dibenzo[b,e][1, 4]diazepin-10(11H)-yl)benzonitrile} was utilized to synthesize the triazapentacyclic ring derivative {12-chloro- 8,15,22-triazapentacyclo[13.7.0. 02,7.09,14.016,21]docosa-1(22),2,4,6,9(14),10, 12,16(21),17,19-decaene}.
Original language | English |
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Pages (from-to) | 2599-2608 |
Number of pages | 10 |
Journal | Advanced Synthesis and Catalysis |
Volume | 356 |
Issue number | 11-12 |
DOIs | |
Publication status | Published - 2014 Aug 11 |
Keywords
- C-N bond formation
- copper catalysts
- dibenzodiazepinones
- tandem processes
- Ullmann coupling
ASJC Scopus subject areas
- Catalysis
- Organic Chemistry
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CCDC 966265: Experimental Crystal Structure Determination
Gawande, S. D. (Creator), Kavala, V. (Creator), Zanwar, M. R. (Creator), Kuo, C. (Creator), Huang, W. (Creator), Kuo, T. (Creator), Huang, H. (Creator), He, C. (Creator) & Yao, C. (Creator), Unknown Publisher, 2014
DOI: 10.5517/cc11fgvs, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc11fgvs&sid=DataCite
Dataset
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CCDC 966266: Experimental Crystal Structure Determination
Gawande, S. D. (Creator), Kavala, V. (Creator), Zanwar, M. R. (Creator), Kuo, C. (Creator), Huang, W. (Creator), Kuo, T. (Creator), Huang, H. (Creator), He, C. (Creator) & Yao, C. (Creator), Unknown Publisher, 2014
DOI: 10.5517/cc11fgwt, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc11fgwt&sid=DataCite
Dataset
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CCDC 966267: Experimental Crystal Structure Determination
Gawande, S. D. (Creator), Kavala, V. (Creator), Zanwar, M. R. (Creator), Kuo, C. (Creator), Huang, W. (Creator), Kuo, T. (Creator), Huang, H. (Creator), He, C. (Creator) & Yao, C. (Creator), Unknown Publisher, 2014
DOI: 10.5517/cc11fgxv, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc11fgxv&sid=DataCite
Dataset