Synthesis of an Se-bridged triiron acyl cluster complex and the Fischer-type carbene complex derived from it: Isolation of rotational isomers

M. Shieh; H. S. Chen; H. H. Chi; C. H. Ueng

doi:10.1021/ic000301+

Synthesis of an Se-bridged triiron acyl cluster complex and the Fischer-type carbene complex derived from it: Isolation of rotational isomers

M. Shieh^*, H. S. Chen, H. H. Chi, C. H. Ueng

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

The synthesis of the acyl cluster complex [Et₄N][(μ₃-Se) Fe₃(CO)₉((μ₃-η¹, η¹,η³-C(O)CHCCH₂] and isolation of the trans and cis isomers of the Fischer-type cluster carbene (μ₃-Se)Fe₃(CO)₉ (μ₃-η¹,η¹, η³-C(OMe)CHCCH₂) are described.

Original language	English
Pages (from-to)	5561-5564
Number of pages	4
Journal	Inorganic Chemistry
Volume	39
Issue number	24
DOIs	https://doi.org/10.1021/ic000301+
Publication status	Published - 2000 Nov 27

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/ic000301+

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title = "Synthesis of an Se-bridged triiron acyl cluster complex and the Fischer-type carbene complex derived from it: Isolation of rotational isomers",

abstract = "The synthesis of the acyl cluster complex [Et4N][(μ3-Se) Fe3(CO)9((μ3-η1, η1,η3-C(O)CHCCH2] and isolation of the trans and cis isomers of the Fischer-type cluster carbene (μ3-Se)Fe3(CO)9 (μ3-η1,η1, η3-C(OMe)CHCCH2) are described.",

author = "M. Shieh and Chen, {H. S.} and Chi, {H. H.} and Ueng, {C. H.}",

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volume = "39",

pages = "5561--5564",

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T1 - Synthesis of an Se-bridged triiron acyl cluster complex and the Fischer-type carbene complex derived from it

T2 - Isolation of rotational isomers

AU - Shieh, M.

AU - Chen, H. S.

AU - Chi, H. H.

AU - Ueng, C. H.

PY - 2000/11/27

Y1 - 2000/11/27

N2 - The synthesis of the acyl cluster complex [Et4N][(μ3-Se) Fe3(CO)9((μ3-η1, η1,η3-C(O)CHCCH2] and isolation of the trans and cis isomers of the Fischer-type cluster carbene (μ3-Se)Fe3(CO)9 (μ3-η1,η1, η3-C(OMe)CHCCH2) are described.

AB - The synthesis of the acyl cluster complex [Et4N][(μ3-Se) Fe3(CO)9((μ3-η1, η1,η3-C(O)CHCCH2] and isolation of the trans and cis isomers of the Fischer-type cluster carbene (μ3-Se)Fe3(CO)9 (μ3-η1,η1, η3-C(OMe)CHCCH2) are described.

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DO - 10.1021/ic000301+

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EP - 5564

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 24

ER -

Synthesis of an Se-bridged triiron acyl cluster complex and the Fischer-type carbene complex derived from it: Isolation of rotational isomers

Abstract

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CCDC 136095: Experimental Crystal Structure Determination

CCDC 136096: Experimental Crystal Structure Determination

CCDC 136094: Experimental Crystal Structure Determination

Cite this

Synthesis of an Se-bridged triiron acyl cluster complex and the Fischer-type carbene complex derived from it: Isolation of rotational isomers

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Datasets

CCDC 136095: Experimental Crystal Structure Determination

CCDC 136096: Experimental Crystal Structure Determination

CCDC 136094: Experimental Crystal Structure Determination

Cite this