Synthesis of an Se-bridged triiron acyl cluster complex and the Fischer-type carbene complex derived from it: Isolation of rotational isomers

Minghuey Shieh, H. S. Chen, H. H. Chi, C. H. Ueng

Research output: Contribution to journal › Article

22 Citations (Scopus)

Abstract

The synthesis of the acyl cluster complex [Et4N][(μ3-Se) Fe3(CO)9((μ3-η1, η1,η3-C(O)CHCCH2] and isolation of the trans and cis isomers of the Fischer-type cluster carbene (μ3-Se)Fe3(CO)9 (μ3-η1,η1, η3-C(OMe)CHCCH2) are described.

Original languageEnglish
Pages (from-to)5561-5564
Number of pages4
JournalInorganic Chemistry
Volume39
Issue number24
DOIs
Publication statusPublished - 2000 Nov 27

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carbenes
Carbon Monoxide
Isomers
isolation
isomers
synthesis
carbene

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

Cite this

Synthesis of an Se-bridged triiron acyl cluster complex and the Fischer-type carbene complex derived from it : Isolation of rotational isomers. / Shieh, Minghuey; Chen, H. S.; Chi, H. H.; Ueng, C. H.

In: Inorganic Chemistry, Vol. 39, No. 24, 27.11.2000, p. 5561-5564.

Research output: Contribution to journal › Article

Shieh, M, Chen, HS, Chi, HH & Ueng, CH 2000, 'Synthesis of an Se-bridged triiron acyl cluster complex and the Fischer-type carbene complex derived from it: Isolation of rotational isomers', Inorganic Chemistry, vol. 39, no. 24, pp. 5561-5564. https://doi.org/10.1021/ic000301+
Shieh M, Chen HS, Chi HH, Ueng CH. Synthesis of an Se-bridged triiron acyl cluster complex and the Fischer-type carbene complex derived from it: Isolation of rotational isomers. Inorganic Chemistry. 2000 Nov 27;39(24):5561-5564. https://doi.org/10.1021/ic000301+
Shieh, Minghuey ; Chen, H. S. ; Chi, H. H. ; Ueng, C. H. / Synthesis of an Se-bridged triiron acyl cluster complex and the Fischer-type carbene complex derived from it : Isolation of rotational isomers. In: Inorganic Chemistry. 2000 ; Vol. 39, No. 24. pp. 5561-5564.
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