Synthesis, crystal structure, and luminescence properties of a new calcium(II) coordination polymer based on L-malic acid

Duraisamy Senthil Raja; Jheng Hong Luo; Ting Guang Chang; Sheng Han Lo; Cheng You Wu; Chia Her Lin

doi:10.1155/2013/980243

Synthesis, crystal structure, and luminescence properties of a new calcium(II) coordination polymer based on L-malic acid

Duraisamy Senthil Raja, Jheng Hong Luo, Ting Guang Chang, Sheng Han Lo, Cheng You Wu, Chia Her Lin^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

A new calcium coordination polymer [Ca(HL-MA)]_n (H ₃L-MA = L-malic acid) has been solvothermally synthesized. The structure of the newly synthesized complex has been determined by single-crystal X-ray diffraction analysis and further characterized by elemental analysis, reflectance UV-Vis & IR spectra, powder X-ray diffraction (PXRD), and thermogravimetric analysis (TGA). The single crystal structure analysis showed that the complex forms three-dimensional framework. The new Ca(II) complex has displayed very high thermal stability which was inferred from TGA and PXRD results. As far as the optical property of the new complex is concerned, the complex emitted its own characteristic sensitized luminescence.

Original language	English
Article number	980243
Journal	Journal of Chemistry
DOIs	https://doi.org/10.1155/2013/980243
Publication status	Published - 2013
Externally published	Yes

ASJC Scopus subject areas

General Chemistry

Access to Document

10.1155/2013/980243

Cite this

@article{cf1338bbdde04c5cbfb11d01c9796bb2,

title = "Synthesis, crystal structure, and luminescence properties of a new calcium(II) coordination polymer based on L-malic acid",

abstract = "A new calcium coordination polymer [Ca(HL-MA)]n (H 3L-MA = L-malic acid) has been solvothermally synthesized. The structure of the newly synthesized complex has been determined by single-crystal X-ray diffraction analysis and further characterized by elemental analysis, reflectance UV-Vis & IR spectra, powder X-ray diffraction (PXRD), and thermogravimetric analysis (TGA). The single crystal structure analysis showed that the complex forms three-dimensional framework. The new Ca(II) complex has displayed very high thermal stability which was inferred from TGA and PXRD results. As far as the optical property of the new complex is concerned, the complex emitted its own characteristic sensitized luminescence.",

author = "Raja, {Duraisamy Senthil} and Luo, {Jheng Hong} and Chang, {Ting Guang} and Lo, {Sheng Han} and Wu, {Cheng You} and Lin, {Chia Her}",

year = "2013",

doi = "10.1155/2013/980243",

language = "English",

journal = "Journal of Chemistry",

issn = "2090-9063",

publisher = "Hindawi Publishing Corporation",

}

TY - JOUR

T1 - Synthesis, crystal structure, and luminescence properties of a new calcium(II) coordination polymer based on L-malic acid

AU - Raja, Duraisamy Senthil

AU - Luo, Jheng Hong

AU - Chang, Ting Guang

AU - Lo, Sheng Han

AU - Wu, Cheng You

AU - Lin, Chia Her

PY - 2013

Y1 - 2013

N2 - A new calcium coordination polymer [Ca(HL-MA)]n (H 3L-MA = L-malic acid) has been solvothermally synthesized. The structure of the newly synthesized complex has been determined by single-crystal X-ray diffraction analysis and further characterized by elemental analysis, reflectance UV-Vis & IR spectra, powder X-ray diffraction (PXRD), and thermogravimetric analysis (TGA). The single crystal structure analysis showed that the complex forms three-dimensional framework. The new Ca(II) complex has displayed very high thermal stability which was inferred from TGA and PXRD results. As far as the optical property of the new complex is concerned, the complex emitted its own characteristic sensitized luminescence.

AB - A new calcium coordination polymer [Ca(HL-MA)]n (H 3L-MA = L-malic acid) has been solvothermally synthesized. The structure of the newly synthesized complex has been determined by single-crystal X-ray diffraction analysis and further characterized by elemental analysis, reflectance UV-Vis & IR spectra, powder X-ray diffraction (PXRD), and thermogravimetric analysis (TGA). The single crystal structure analysis showed that the complex forms three-dimensional framework. The new Ca(II) complex has displayed very high thermal stability which was inferred from TGA and PXRD results. As far as the optical property of the new complex is concerned, the complex emitted its own characteristic sensitized luminescence.

UR - http://www.scopus.com/inward/record.url?scp=84879327976&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84879327976&partnerID=8YFLogxK

U2 - 10.1155/2013/980243

DO - 10.1155/2013/980243

M3 - Article

AN - SCOPUS:84879327976

SN - 2090-9063

JO - Journal of Chemistry

JF - Journal of Chemistry

M1 - 980243

ER -

Synthesis, crystal structure, and luminescence properties of a new calcium(II) coordination polymer based on L-malic acid

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this