Synthesis and structural characterization of dimolybdenum(IV) and molybdenum(VI) complexes with trisbenzenethiolatophosphine ligands

Hua Fen Hsu; Wan Yu Peng; Zung Ying Li; Ru Rong Wu; Ju Hsiou Liao; Yu Wang; Yi Hung Liu; Minghuey Shieh; Ting Shen Kuo

doi:10.1016/j.ica.2004.12.020

Synthesis and structural characterization of dimolybdenum(IV) and molybdenum(VI) complexes with trisbenzenethiolatophosphine ligands

Hua Fen Hsu^*, Wan Yu Peng, Zung Ying Li, Ru Rong Wu, Ju Hsiou Liao, Yu Wang, Yi Hung Liu, Minghuey Shieh, Ting Shen Kuo

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

The synthesis and crystal structures of two high valent molybdenum complexes containing trisbenzenethiolatophosphine ligands, [Mo ₂(PS3)₂(PS3H)] (1) and [Mo(PS3″)₂] (2), where PS3 = [P(C₆H₄-2-S)₃]^3-, PS3H = [P(C₆H₄-2-S)₂(C₆H ₄-2-SH)]^2-, and PS3″ = [P(C₆H ₃-3-Me₃Si-2-S)₃]^3-, are described. Compound 1 is a dimeric Mo(IV) species containing three PS3 ligands with an uncoordinated thiol group. An intramolecular hydrogen bonding S-H⋯S was found in the structure. Two molybdenum ions are bridged by three thiolates. The geometry can be described as two pentagonal bipyramids sharing a triangle face formed by three bridging S atoms. Compound 2 is a Mo(VI) species binding with two tetradentate PS3″ ligands. The eight-coordinate molybdenum center adopts a dodecahedral geometry.

Original language	English
Pages (from-to)	2149-2154
Number of pages	6
Journal	Inorganica Chimica Acta
Volume	358
Issue number	6
DOIs	https://doi.org/10.1016/j.ica.2004.12.020
Publication status	Published - 2005 Mar 30

Keywords

Dodecahedral geometry
Eight-coordinate
Molybdenum complexes
P NMR
S-donor ligand

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.ica.2004.12.020

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@article{69b6bcb33c204973862f28b307309154,

title = "Synthesis and structural characterization of dimolybdenum(IV) and molybdenum(VI) complexes with trisbenzenethiolatophosphine ligands",

abstract = "The synthesis and crystal structures of two high valent molybdenum complexes containing trisbenzenethiolatophosphine ligands, [Mo 2(PS3)2(PS3H)] (1) and [Mo(PS3″)2] (2), where PS3 = [P(C6H4-2-S)3]3-, PS3H = [P(C6H4-2-S)2(C6H 4-2-SH)]2-, and PS3″ = [P(C6H 3-3-Me3Si-2-S)3]3-, are described. Compound 1 is a dimeric Mo(IV) species containing three PS3 ligands with an uncoordinated thiol group. An intramolecular hydrogen bonding S-H⋯S was found in the structure. Two molybdenum ions are bridged by three thiolates. The geometry can be described as two pentagonal bipyramids sharing a triangle face formed by three bridging S atoms. Compound 2 is a Mo(VI) species binding with two tetradentate PS3″ ligands. The eight-coordinate molybdenum center adopts a dodecahedral geometry.",

keywords = "Dodecahedral geometry, Eight-coordinate, Molybdenum complexes, P NMR, S-donor ligand",

author = "Hsu, {Hua Fen} and Peng, {Wan Yu} and Li, {Zung Ying} and Wu, {Ru Rong} and Liao, {Ju Hsiou} and Yu Wang and Liu, {Yi Hung} and Minghuey Shieh and Kuo, {Ting Shen}",

note = "Funding Information: We thank the National Science Council in Taiwan (NSC 92-2113-M-006-018-) for generous support of this work.",

year = "2005",

month = mar,

day = "30",

doi = "10.1016/j.ica.2004.12.020",

language = "English",

volume = "358",

pages = "2149--2154",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier BV",

number = "6",

}

TY - JOUR

T1 - Synthesis and structural characterization of dimolybdenum(IV) and molybdenum(VI) complexes with trisbenzenethiolatophosphine ligands

AU - Hsu, Hua Fen

AU - Peng, Wan Yu

AU - Li, Zung Ying

AU - Wu, Ru Rong

AU - Liao, Ju Hsiou

AU - Wang, Yu

AU - Liu, Yi Hung

AU - Shieh, Minghuey

AU - Kuo, Ting Shen

N1 - Funding Information: We thank the National Science Council in Taiwan (NSC 92-2113-M-006-018-) for generous support of this work.

PY - 2005/3/30

Y1 - 2005/3/30

N2 - The synthesis and crystal structures of two high valent molybdenum complexes containing trisbenzenethiolatophosphine ligands, [Mo 2(PS3)2(PS3H)] (1) and [Mo(PS3″)2] (2), where PS3 = [P(C6H4-2-S)3]3-, PS3H = [P(C6H4-2-S)2(C6H 4-2-SH)]2-, and PS3″ = [P(C6H 3-3-Me3Si-2-S)3]3-, are described. Compound 1 is a dimeric Mo(IV) species containing three PS3 ligands with an uncoordinated thiol group. An intramolecular hydrogen bonding S-H⋯S was found in the structure. Two molybdenum ions are bridged by three thiolates. The geometry can be described as two pentagonal bipyramids sharing a triangle face formed by three bridging S atoms. Compound 2 is a Mo(VI) species binding with two tetradentate PS3″ ligands. The eight-coordinate molybdenum center adopts a dodecahedral geometry.

AB - The synthesis and crystal structures of two high valent molybdenum complexes containing trisbenzenethiolatophosphine ligands, [Mo 2(PS3)2(PS3H)] (1) and [Mo(PS3″)2] (2), where PS3 = [P(C6H4-2-S)3]3-, PS3H = [P(C6H4-2-S)2(C6H 4-2-SH)]2-, and PS3″ = [P(C6H 3-3-Me3Si-2-S)3]3-, are described. Compound 1 is a dimeric Mo(IV) species containing three PS3 ligands with an uncoordinated thiol group. An intramolecular hydrogen bonding S-H⋯S was found in the structure. Two molybdenum ions are bridged by three thiolates. The geometry can be described as two pentagonal bipyramids sharing a triangle face formed by three bridging S atoms. Compound 2 is a Mo(VI) species binding with two tetradentate PS3″ ligands. The eight-coordinate molybdenum center adopts a dodecahedral geometry.

KW - Dodecahedral geometry

KW - Eight-coordinate

KW - Molybdenum complexes

KW - P NMR

KW - S-donor ligand

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U2 - 10.1016/j.ica.2004.12.020

DO - 10.1016/j.ica.2004.12.020

M3 - Article

AN - SCOPUS:14844314164

SN - 0020-1693

VL - 358

SP - 2149

EP - 2154

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 6

ER -

Synthesis and structural characterization of dimolybdenum(IV) and molybdenum(VI) complexes with trisbenzenethiolatophosphine ligands

Abstract

Keywords

ASJC Scopus subject areas

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CCDC 255991: Experimental Crystal Structure Determination

CCDC 255990: Experimental Crystal Structure Determination

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Synthesis and structural characterization of dimolybdenum(IV) and molybdenum(VI) complexes with trisbenzenethiolatophosphine ligands

Abstract

Keywords

ASJC Scopus subject areas

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Other files and links

Fingerprint

Datasets

CCDC 255991: Experimental Crystal Structure Determination

CCDC 255990: Experimental Crystal Structure Determination

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