Synthesis and structural characterization of dimolybdenum(IV) and molybdenum(VI) complexes with trisbenzenethiolatophosphine ligands

Hua Fen Hsu, Wan Yu Peng, Zung Ying Li, Ru Rong Wu, Ju Hsiou Liao, Yu Wang, Yi Hung Liu, Minghuey Shieh, Ting Shen Kuo

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

The synthesis and crystal structures of two high valent molybdenum complexes containing trisbenzenethiolatophosphine ligands, [Mo 2(PS3)2(PS3H)] (1) and [Mo(PS3″)2] (2), where PS3 = [P(C6H4-2-S)3]3-, PS3H = [P(C6H4-2-S)2(C6H 4-2-SH)]2-, and PS3″ = [P(C6H 3-3-Me3Si-2-S)3]3-, are described. Compound 1 is a dimeric Mo(IV) species containing three PS3 ligands with an uncoordinated thiol group. An intramolecular hydrogen bonding S-H⋯S was found in the structure. Two molybdenum ions are bridged by three thiolates. The geometry can be described as two pentagonal bipyramids sharing a triangle face formed by three bridging S atoms. Compound 2 is a Mo(VI) species binding with two tetradentate PS3″ ligands. The eight-coordinate molybdenum center adopts a dodecahedral geometry.

Original languageEnglish
Pages (from-to)2149-2154
Number of pages6
JournalInorganica Chimica Acta
Volume358
Issue number6
DOIs
Publication statusPublished - 2005 Mar 30

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Molybdenum
molybdenum
Ligands
ligands
synthesis
Geometry
geometry
Sulfhydryl Compounds
thiols
triangles
Hydrogen bonds
Crystal structure
Ions
Atoms
crystal structure
hydrogen
atoms
ions

Keywords

  • P NMR
  • Dodecahedral geometry
  • Eight-coordinate
  • Molybdenum complexes
  • S-donor ligand

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

Synthesis and structural characterization of dimolybdenum(IV) and molybdenum(VI) complexes with trisbenzenethiolatophosphine ligands. / Hsu, Hua Fen; Peng, Wan Yu; Li, Zung Ying; Wu, Ru Rong; Liao, Ju Hsiou; Wang, Yu; Liu, Yi Hung; Shieh, Minghuey; Kuo, Ting Shen.

In: Inorganica Chimica Acta, Vol. 358, No. 6, 30.03.2005, p. 2149-2154.

Research output: Contribution to journalArticle

Hsu, Hua Fen ; Peng, Wan Yu ; Li, Zung Ying ; Wu, Ru Rong ; Liao, Ju Hsiou ; Wang, Yu ; Liu, Yi Hung ; Shieh, Minghuey ; Kuo, Ting Shen. / Synthesis and structural characterization of dimolybdenum(IV) and molybdenum(VI) complexes with trisbenzenethiolatophosphine ligands. In: Inorganica Chimica Acta. 2005 ; Vol. 358, No. 6. pp. 2149-2154.
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T1 - Synthesis and structural characterization of dimolybdenum(IV) and molybdenum(VI) complexes with trisbenzenethiolatophosphine ligands

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AU - Peng, Wan Yu

AU - Li, Zung Ying

AU - Wu, Ru Rong

AU - Liao, Ju Hsiou

AU - Wang, Yu

AU - Liu, Yi Hung

AU - Shieh, Minghuey

AU - Kuo, Ting Shen

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N2 - The synthesis and crystal structures of two high valent molybdenum complexes containing trisbenzenethiolatophosphine ligands, [Mo 2(PS3)2(PS3H)] (1) and [Mo(PS3″)2] (2), where PS3 = [P(C6H4-2-S)3]3-, PS3H = [P(C6H4-2-S)2(C6H 4-2-SH)]2-, and PS3″ = [P(C6H 3-3-Me3Si-2-S)3]3-, are described. Compound 1 is a dimeric Mo(IV) species containing three PS3 ligands with an uncoordinated thiol group. An intramolecular hydrogen bonding S-H⋯S was found in the structure. Two molybdenum ions are bridged by three thiolates. The geometry can be described as two pentagonal bipyramids sharing a triangle face formed by three bridging S atoms. Compound 2 is a Mo(VI) species binding with two tetradentate PS3″ ligands. The eight-coordinate molybdenum center adopts a dodecahedral geometry.

AB - The synthesis and crystal structures of two high valent molybdenum complexes containing trisbenzenethiolatophosphine ligands, [Mo 2(PS3)2(PS3H)] (1) and [Mo(PS3″)2] (2), where PS3 = [P(C6H4-2-S)3]3-, PS3H = [P(C6H4-2-S)2(C6H 4-2-SH)]2-, and PS3″ = [P(C6H 3-3-Me3Si-2-S)3]3-, are described. Compound 1 is a dimeric Mo(IV) species containing three PS3 ligands with an uncoordinated thiol group. An intramolecular hydrogen bonding S-H⋯S was found in the structure. Two molybdenum ions are bridged by three thiolates. The geometry can be described as two pentagonal bipyramids sharing a triangle face formed by three bridging S atoms. Compound 2 is a Mo(VI) species binding with two tetradentate PS3″ ligands. The eight-coordinate molybdenum center adopts a dodecahedral geometry.

KW - P NMR

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KW - Molybdenum complexes

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