Synthesis and Characterization of the New Series of Chromium-Group 15 Hydride Complexes [Et4N]2[He{Cr(CO)5}3] (E = As, Sb)

Jiann Jang Cherng; Gene Hsiang Lee; Shie Ming Peng; Chuen Her Ueng; Minghuey Shieh

doi:10.1021/om990717z

Synthesis and Characterization of the New Series of Chromium-Group 15 Hydride Complexes [Et₄N]₂[He{Cr(CO)₅}₃] (E = As, Sb)

Jiann Jang Cherng, Gene Hsiang Lee, Shie Ming Peng, Chuen Her Ueng, Minghuey Shieh^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

The new series of trigonal-pyramidal chromium complexes [HE{Cr(CO)₅)₃]^2- (E=As (Ia), Sb (Ib)) were obtained from the reactions of E₂O₃ (E = As, Sb) with Cr(CO)₆ in concentrated KOH methanolic solution. These are the first examples of group 6 complexes containing E-H fragments (E = As, Sb), and the hydrogens are shown to be more hydridic than those in the related iron complexes due to the more electropositive character of Cr.

Original language	English
Pages (from-to)	213-215
Number of pages	3
Journal	Organometallics
Volume	19
Issue number	3
DOIs	https://doi.org/10.1021/om990717z
Publication status	Published - 2000 Feb 7

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om990717z

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abstract = "The new series of trigonal-pyramidal chromium complexes [HE{Cr(CO)5)3]2- (E=As (Ia), Sb (Ib)) were obtained from the reactions of E2O3 (E = As, Sb) with Cr(CO)6 in concentrated KOH methanolic solution. These are the first examples of group 6 complexes containing E-H fragments (E = As, Sb), and the hydrogens are shown to be more hydridic than those in the related iron complexes due to the more electropositive character of Cr.",

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AU - Cherng, Jiann Jang

AU - Lee, Gene Hsiang

AU - Peng, Shie Ming

AU - Ueng, Chuen Her

AU - Shieh, Minghuey

PY - 2000/2/7

Y1 - 2000/2/7

N2 - The new series of trigonal-pyramidal chromium complexes [HE{Cr(CO)5)3]2- (E=As (Ia), Sb (Ib)) were obtained from the reactions of E2O3 (E = As, Sb) with Cr(CO)6 in concentrated KOH methanolic solution. These are the first examples of group 6 complexes containing E-H fragments (E = As, Sb), and the hydrogens are shown to be more hydridic than those in the related iron complexes due to the more electropositive character of Cr.

AB - The new series of trigonal-pyramidal chromium complexes [HE{Cr(CO)5)3]2- (E=As (Ia), Sb (Ib)) were obtained from the reactions of E2O3 (E = As, Sb) with Cr(CO)6 in concentrated KOH methanolic solution. These are the first examples of group 6 complexes containing E-H fragments (E = As, Sb), and the hydrogens are shown to be more hydridic than those in the related iron complexes due to the more electropositive character of Cr.

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Synthesis and Characterization of the New Series of Chromium-Group 15 Hydride Complexes [Et₄N]₂[He{Cr(CO)₅}₃] (E = As, Sb)

Abstract

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CCDC 161534: Experimental Crystal Structure Determination

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Synthesis and Characterization of the New Series of Chromium-Group 15 Hydride Complexes [Et4N]2[He{Cr(CO)5}3] (E = As, Sb)

Abstract

ASJC Scopus subject areas

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CCDC 161534: Experimental Crystal Structure Determination

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Synthesis and Characterization of the New Series of Chromium-Group 15 Hydride Complexes [Et₄N]₂[He{Cr(CO)₅}₃] (E = As, Sb)