Synthesis and characterization of pentadienyl-iridium(III) and-rhodium(III) complexes

Chia Chun Chen; Rai Shung Liu

doi:10.1016/0022-328X(87)87172-3

Synthesis and characterization of pentadienyl-iridium(III) and-rhodium(III) complexes

Chia Chun Chen^*, Rai Shung Liu

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

1-Halopen-2,4-dienes CH₂CHCHCHCH₂X (X = Cl, Br) undergo facile oxidative addition with complexes of the type trans-MCl(CO)(PR₃)₂ (M = Rh, PR₃ = PMe₂Ph; M = Ir, PR₃ = PMe₂Ph, PPh₃). The configurations of these adducts were elucidated by combining their far-IR, ¹H and ³¹P NMR spectra.

Original language	English
Pages (from-to)	249-255
Number of pages	7
Journal	Journal of Organometallic Chemistry
Volume	336
Issue number	1-2
DOIs	https://doi.org/10.1016/0022-328X(87)87172-3
Publication status	Published - 1987 Dec 8
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/0022-328X(87)87172-3

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title = "Synthesis and characterization of pentadienyl-iridium(III) and-rhodium(III) complexes",

abstract = "1-Halopen-2,4-dienes CH2CHCHCHCH2X (X = Cl, Br) undergo facile oxidative addition with complexes of the type trans-MCl(CO)(PR3)2 (M = Rh, PR3 = PMe2Ph; M = Ir, PR3 = PMe2Ph, PPh3). The configurations of these adducts were elucidated by combining their far-IR, 1H and 31P NMR spectra.",

author = "Chen, {Chia Chun} and Liu, {Rai Shung}",

year = "1987",

month = dec,

day = "8",

doi = "10.1016/0022-328X(87)87172-3",

language = "English",

volume = "336",

pages = "249--255",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

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number = "1-2",

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T1 - Synthesis and characterization of pentadienyl-iridium(III) and-rhodium(III) complexes

AU - Chen, Chia Chun

AU - Liu, Rai Shung

PY - 1987/12/8

Y1 - 1987/12/8

N2 - 1-Halopen-2,4-dienes CH2CHCHCHCH2X (X = Cl, Br) undergo facile oxidative addition with complexes of the type trans-MCl(CO)(PR3)2 (M = Rh, PR3 = PMe2Ph; M = Ir, PR3 = PMe2Ph, PPh3). The configurations of these adducts were elucidated by combining their far-IR, 1H and 31P NMR spectra.

AB - 1-Halopen-2,4-dienes CH2CHCHCHCH2X (X = Cl, Br) undergo facile oxidative addition with complexes of the type trans-MCl(CO)(PR3)2 (M = Rh, PR3 = PMe2Ph; M = Ir, PR3 = PMe2Ph, PPh3). The configurations of these adducts were elucidated by combining their far-IR, 1H and 31P NMR spectra.

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U2 - 10.1016/0022-328X(87)87172-3

DO - 10.1016/0022-328X(87)87172-3

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AN - SCOPUS:45949113892

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JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1-2

ER -

Synthesis and characterization of pentadienyl-iridium(III) and-rhodium(III) complexes

Abstract

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