Synthesis and characterization of pentadienyl-iridium(III) and-rhodium(III) complexes

Chia Chun Chen*, Rai Shung Liu

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)


1-Halopen-2,4-dienes CH2CHCHCHCH2X (X = Cl, Br) undergo facile oxidative addition with complexes of the type trans-MCl(CO)(PR3)2 (M = Rh, PR3 = PMe2Ph; M = Ir, PR3 = PMe2Ph, PPh3). The configurations of these adducts were elucidated by combining their far-IR, 1H and 31P NMR spectra.

Original languageEnglish
Pages (from-to)249-255
Number of pages7
JournalJournal of Organometallic Chemistry
Issue number1-2
Publication statusPublished - 1987 Dec 8
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry


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