Synthesis and characterization of pentadienyl-iridium(III) and-rhodium(III) complexes

Chia Chun Chen, Rai Shung Liu

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Abstract

1-Halopen-2,4-dienes CH2CHCHCHCH2X (X = Cl, Br) undergo facile oxidative addition with complexes of the type trans-MCl(CO)(PR3)2 (M = Rh, PR3 = PMe2Ph; M = Ir, PR3 = PMe2Ph, PPh3). The configurations of these adducts were elucidated by combining their far-IR, 1H and 31P NMR spectra.

Original languageEnglish
Pages (from-to)249-255
Number of pages7
JournalJournal of Organometallic Chemistry
Volume336
Issue number1-2
DOIs
Publication statusPublished - 1987 Dec 8

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ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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