Synthesis and characterization of π-extended bowl-shaped π-conjugated molecules

Toru Amaya, Koichi Mori, Hsyueh Liang Wu, Satoshi Ishida, Jun Ichi Nakamura, Kazuhiko Murata, Toshikazu Hirao

Research output: Contribution to journalArticle

52 Citations (Scopus)

Abstract

A series of π-extended bowl-shaped π-conjugated compounds were synthesized from sumanene and characterized, and among them the terthiophene derivative showed a remarkable red-shifted absorption and small band gap, which was rationalized by molecular orbital calculation.

Original languageEnglish
Pages (from-to)1902-1904
Number of pages3
JournalChemical Communications
Issue number19
DOIs
Publication statusPublished - 2007 Jun 29

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Orbital calculations
Molecular orbitals
Energy gap
Derivatives
Molecules
alpha-terthienyl
sumanene

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

Amaya, T., Mori, K., Wu, H. L., Ishida, S., Nakamura, J. I., Murata, K., & Hirao, T. (2007). Synthesis and characterization of π-extended bowl-shaped π-conjugated molecules. Chemical Communications, (19), 1902-1904. https://doi.org/10.1039/b701322a

Synthesis and characterization of π-extended bowl-shaped π-conjugated molecules. / Amaya, Toru; Mori, Koichi; Wu, Hsyueh Liang; Ishida, Satoshi; Nakamura, Jun Ichi; Murata, Kazuhiko; Hirao, Toshikazu.

In: Chemical Communications, No. 19, 29.06.2007, p. 1902-1904.

Research output: Contribution to journalArticle

Amaya, T, Mori, K, Wu, HL, Ishida, S, Nakamura, JI, Murata, K & Hirao, T 2007, 'Synthesis and characterization of π-extended bowl-shaped π-conjugated molecules', Chemical Communications, no. 19, pp. 1902-1904. https://doi.org/10.1039/b701322a
Amaya, Toru ; Mori, Koichi ; Wu, Hsyueh Liang ; Ishida, Satoshi ; Nakamura, Jun Ichi ; Murata, Kazuhiko ; Hirao, Toshikazu. / Synthesis and characterization of π-extended bowl-shaped π-conjugated molecules. In: Chemical Communications. 2007 ; No. 19. pp. 1902-1904.
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