Suppression of Background Emission from High Vibrational Levels in the Excited State through Vibronic Mixing in Supersonic Jet Spectrometry by Using Synchronous Scan Luminescence

Cheng-Huang Lin, Totaro Imasaka, Nobuhiko Ishibashi

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

When a sample molecule is excited to high vibrational levels in the excited state, rapid intramolecular relaxation occurs by an interaction with a dense manifold of vibrational levels in the ground state. Due to vibronic mixing, a combination of vibrational quanta is redistributed and the state is no longer identical with the initial state excited. Therefore, a complicated and broad-band structure appears in a conventional excitation spectrum, due to breakdown of selection rules. This common feature in supersonic jet spectrometry makes It difficult to assign a specific component even for a sample containing only a single interference compound. For example, selective detection of β-naphthol is difficult for a sample containing anthracene, and this situation is similar to m-toluidine and 2-methylnaphthalene. However, this unwanted photoemission is completely suppressed by a combination of supersonic Jet spectrometry and synchronous scan luminescence spectrometry monitoring resonance fluorescence (SSJ/R-SSL). Furthermore, the number of spectral lines is reduced, giving a simpler spectrum. Thus SSJ/R-SSL spectrometry provides a useful analytical means for selective analysis of organic molecules such as polycyclic aromatic hydrocarbons.

Original languageEnglish
Pages (from-to)2346-2348
Number of pages3
JournalAnalytical Chemistry
Volume63
Issue number20
DOIs
Publication statusPublished - 1991 Oct 1

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Luminescence
Excited states
Spectrometry
Spectrum Analysis
Naphthols
Molecules
Polycyclic Aromatic Hydrocarbons
Photoemission
Band structure
Ground state
Fluorescence
Monitoring

ASJC Scopus subject areas

  • Analytical Chemistry

Cite this

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title = "Suppression of Background Emission from High Vibrational Levels in the Excited State through Vibronic Mixing in Supersonic Jet Spectrometry by Using Synchronous Scan Luminescence",
abstract = "When a sample molecule is excited to high vibrational levels in the excited state, rapid intramolecular relaxation occurs by an interaction with a dense manifold of vibrational levels in the ground state. Due to vibronic mixing, a combination of vibrational quanta is redistributed and the state is no longer identical with the initial state excited. Therefore, a complicated and broad-band structure appears in a conventional excitation spectrum, due to breakdown of selection rules. This common feature in supersonic jet spectrometry makes It difficult to assign a specific component even for a sample containing only a single interference compound. For example, selective detection of β-naphthol is difficult for a sample containing anthracene, and this situation is similar to m-toluidine and 2-methylnaphthalene. However, this unwanted photoemission is completely suppressed by a combination of supersonic Jet spectrometry and synchronous scan luminescence spectrometry monitoring resonance fluorescence (SSJ/R-SSL). Furthermore, the number of spectral lines is reduced, giving a simpler spectrum. Thus SSJ/R-SSL spectrometry provides a useful analytical means for selective analysis of organic molecules such as polycyclic aromatic hydrocarbons.",
author = "Cheng-Huang Lin and Totaro Imasaka and Nobuhiko Ishibashi",
year = "1991",
month = "10",
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language = "English",
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journal = "Analytical Chemistry",
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T1 - Suppression of Background Emission from High Vibrational Levels in the Excited State through Vibronic Mixing in Supersonic Jet Spectrometry by Using Synchronous Scan Luminescence

AU - Lin, Cheng-Huang

AU - Imasaka, Totaro

AU - Ishibashi, Nobuhiko

PY - 1991/10/1

Y1 - 1991/10/1

N2 - When a sample molecule is excited to high vibrational levels in the excited state, rapid intramolecular relaxation occurs by an interaction with a dense manifold of vibrational levels in the ground state. Due to vibronic mixing, a combination of vibrational quanta is redistributed and the state is no longer identical with the initial state excited. Therefore, a complicated and broad-band structure appears in a conventional excitation spectrum, due to breakdown of selection rules. This common feature in supersonic jet spectrometry makes It difficult to assign a specific component even for a sample containing only a single interference compound. For example, selective detection of β-naphthol is difficult for a sample containing anthracene, and this situation is similar to m-toluidine and 2-methylnaphthalene. However, this unwanted photoemission is completely suppressed by a combination of supersonic Jet spectrometry and synchronous scan luminescence spectrometry monitoring resonance fluorescence (SSJ/R-SSL). Furthermore, the number of spectral lines is reduced, giving a simpler spectrum. Thus SSJ/R-SSL spectrometry provides a useful analytical means for selective analysis of organic molecules such as polycyclic aromatic hydrocarbons.

AB - When a sample molecule is excited to high vibrational levels in the excited state, rapid intramolecular relaxation occurs by an interaction with a dense manifold of vibrational levels in the ground state. Due to vibronic mixing, a combination of vibrational quanta is redistributed and the state is no longer identical with the initial state excited. Therefore, a complicated and broad-band structure appears in a conventional excitation spectrum, due to breakdown of selection rules. This common feature in supersonic jet spectrometry makes It difficult to assign a specific component even for a sample containing only a single interference compound. For example, selective detection of β-naphthol is difficult for a sample containing anthracene, and this situation is similar to m-toluidine and 2-methylnaphthalene. However, this unwanted photoemission is completely suppressed by a combination of supersonic Jet spectrometry and synchronous scan luminescence spectrometry monitoring resonance fluorescence (SSJ/R-SSL). Furthermore, the number of spectral lines is reduced, giving a simpler spectrum. Thus SSJ/R-SSL spectrometry provides a useful analytical means for selective analysis of organic molecules such as polycyclic aromatic hydrocarbons.

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