Supersonic jet/time-of-flight mass spectrometry of adenine using nanosecond and femtosecond lasers

Cheng Huang Lin, Junichi Matsumoto, Satoshi Ohtake, Totaro Imasaka*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

10 Citations (Scopus)

Abstract

Mass spectra and ionization efficiencies of adenine were measured, with nanosecond (15 ns) and femtosecond (500 fs) laser pulses at identical energy levels. A molecular ion is clearly observed in both spectra, but the efficiency is improved 10-fold when a femtosecond laser is used, indicating the distinct advantage of ultrashort laser pulses for multiphoton ionization of nucleobases in supersonic jet spectrometry.

Original languageEnglish
Pages (from-to)1925-1929
Number of pages5
JournalTalanta
Volume43
Issue number11
DOIs
Publication statusPublished - 1996 Nov
Externally publishedYes

Keywords

  • Adenine
  • Ionization efficiencies
  • Lasers
  • Mass spectra
  • Nucleobases

ASJC Scopus subject areas

  • Analytical Chemistry

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