Abstract
Mass spectra and ionization efficiencies of adenine were measured, with nanosecond (15 ns) and femtosecond (500 fs) laser pulses at identical energy levels. A molecular ion is clearly observed in both spectra, but the efficiency is improved 10-fold when a femtosecond laser is used, indicating the distinct advantage of ultrashort laser pulses for multiphoton ionization of nucleobases in supersonic jet spectrometry.
Original language | English |
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Pages (from-to) | 1925-1929 |
Number of pages | 5 |
Journal | Talanta |
Volume | 43 |
Issue number | 11 |
DOIs | |
Publication status | Published - 1996 Nov |
Externally published | Yes |
Keywords
- Adenine
- Ionization efficiencies
- Lasers
- Mass spectra
- Nucleobases
ASJC Scopus subject areas
- Analytical Chemistry