Study on the Nucleophilic Addition to (η4‐Cis‐1‐Methoxy‐1,3‐Butadiene)Iron Tricarbonyl Complex

Ming‐Chang P. Yeh; Chih‐Hong ‐H Chu; Mei‐Ling ‐L Sun; Kuo‐Ping ‐P Kang

doi:10.1002/jccs.199000075

Study on the Nucleophilic Addition to (η⁴‐Cis‐1‐Methoxy‐1,3‐Butadiene)Iron Tricarbonyl Complex

Ming‐Chang P. Yeh^*, Chih‐Hong ‐H Chu, Mei‐Ling ‐L Sun, Kuo‐Ping ‐P Kang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

Reaction of the reactive carbanion with (η⁴‐cis‐l‐methoxy‐1,3‐butadiene)Fe(CO)3, followed by acid quenching, generates the C‐1 substitution product (27%) together with the regular C‐2 adduct (71%). A very stable ferracyclopentanone was isolated and its x‐ray diffraction analysis determined.

Original language	English
Pages (from-to)	547-556
Number of pages	10
Journal	Journal of the Chinese Chemical Society
Volume	37
Issue number	6
DOIs	https://doi.org/10.1002/jccs.199000075
Publication status	Published - 1990 Dec
Externally published	Yes

Keywords

CO insertion
Cine substitution
Reductive elimination
a‐methoxy elimination
p‐hydride elimination

ASJC Scopus subject areas

General Chemistry

Access to Document

10.1002/jccs.199000075

Cite this

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title = "Study on the Nucleophilic Addition to (η4‐Cis‐1‐Methoxy‐1,3‐Butadiene)Iron Tricarbonyl Complex",

abstract = "Reaction of the reactive carbanion with (η4‐cis‐l‐methoxy‐1,3‐butadiene)Fe(CO)3, followed by acid quenching, generates the C‐1 substitution product (27%) together with the regular C‐2 adduct (71%). A very stable ferracyclopentanone was isolated and its x‐ray diffraction analysis determined.",

keywords = "CO insertion, Cine substitution, Reductive elimination, a‐methoxy elimination, p‐hydride elimination",

author = "Yeh, {Ming‐Chang P.} and Chu, {Chih‐Hong ‐H} and Sun, {Mei‐Ling ‐L} and Kang, {Kuo‐Ping ‐P}",

year = "1990",

month = dec,

doi = "10.1002/jccs.199000075",

language = "English",

volume = "37",

pages = "547--556",

journal = "Journal of the Chinese Chemical Society",

issn = "0009-4536",

publisher = "Chinese Chemical Society",

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TY - JOUR

T1 - Study on the Nucleophilic Addition to (η4‐Cis‐1‐Methoxy‐1,3‐Butadiene)Iron Tricarbonyl Complex

AU - Yeh, Ming‐Chang P.

AU - Chu, Chih‐Hong ‐H

AU - Sun, Mei‐Ling ‐L

AU - Kang, Kuo‐Ping ‐P

PY - 1990/12

Y1 - 1990/12

N2 - Reaction of the reactive carbanion with (η4‐cis‐l‐methoxy‐1,3‐butadiene)Fe(CO)3, followed by acid quenching, generates the C‐1 substitution product (27%) together with the regular C‐2 adduct (71%). A very stable ferracyclopentanone was isolated and its x‐ray diffraction analysis determined.

AB - Reaction of the reactive carbanion with (η4‐cis‐l‐methoxy‐1,3‐butadiene)Fe(CO)3, followed by acid quenching, generates the C‐1 substitution product (27%) together with the regular C‐2 adduct (71%). A very stable ferracyclopentanone was isolated and its x‐ray diffraction analysis determined.

KW - CO insertion

KW - Cine substitution

KW - Reductive elimination

KW - a‐methoxy elimination

KW - p‐hydride elimination

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JF - Journal of the Chinese Chemical Society

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