Structural interconversion controlled by hydrogen-bond interactions

A mononuclear copper triamine complex and a polynuclear copper triamine sheet

Way-Zen Lee, Ya Lin Kang, Tzu Li Wang, Chan Cheng Su, Ting Shen Kuo

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

Because of the steric hindrance caused by the large bite angles of the employed dipropylenetriamine (dpt) ligand to the copper center, a five-coordinated copper triamine complex, [Cu(η3-dpt) (η2-dpt)](ClO4)2 (1), was prepared and structurally characterized. When water was added to a methanol solution of 1, the discrete mononuclear copper complex 1 was converted to a two-dimensional zigzag layer, and this conversion behavior was reversible as water was removed.

Original languageEnglish
Pages (from-to)2614-2616
Number of pages3
JournalCrystal Growth and Design
Volume8
Issue number8
DOIs
Publication statusPublished - 2008 Aug 1

Fingerprint

Copper
Hydrogen bonds
hydrogen bonds
copper
Water
interactions
water
Methanol
methyl alcohol
Ligands
ligands
perchlorate

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Structural interconversion controlled by hydrogen-bond interactions : A mononuclear copper triamine complex and a polynuclear copper triamine sheet. / Lee, Way-Zen; Kang, Ya Lin; Wang, Tzu Li; Su, Chan Cheng; Kuo, Ting Shen.

In: Crystal Growth and Design, Vol. 8, No. 8, 01.08.2008, p. 2614-2616.

Research output: Contribution to journalArticle

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