Structural interconversion controlled by hydrogen-bond interactions: A mononuclear copper triamine complex and a polynuclear copper triamine sheet

Way-Zen Lee; Ya Lin Kang; Tzu Li Wang; Chan Cheng Su; Ting Shen Kuo

doi:10.1021/cg8002977

Structural interconversion controlled by hydrogen-bond interactions: A mononuclear copper triamine complex and a polynuclear copper triamine sheet

Way-Zen Lee, Ya Lin Kang, Tzu Li Wang, Chan Cheng Su, Ting Shen Kuo

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

Because of the steric hindrance caused by the large bite angles of the employed dipropylenetriamine (dpt) ligand to the copper center, a five-coordinated copper triamine complex, [Cu(η³-dpt) (η²-dpt)](ClO₄)₂ (1), was prepared and structurally characterized. When water was added to a methanol solution of 1, the discrete mononuclear copper complex 1 was converted to a two-dimensional zigzag layer, and this conversion behavior was reversible as water was removed.

Original language	English
Pages (from-to)	2614-2616
Number of pages	3
Journal	Crystal Growth and Design
Volume	8
Issue number	8
DOIs	https://doi.org/10.1021/cg8002977
Publication status	Published - 2008 Aug

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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abstract = "Because of the steric hindrance caused by the large bite angles of the employed dipropylenetriamine (dpt) ligand to the copper center, a five-coordinated copper triamine complex, [Cu(η3-dpt) (η2-dpt)](ClO4)2 (1), was prepared and structurally characterized. When water was added to a methanol solution of 1, the discrete mononuclear copper complex 1 was converted to a two-dimensional zigzag layer, and this conversion behavior was reversible as water was removed.",

author = "Way-Zen Lee and Kang, {Ya Lin} and Wang, {Tzu Li} and Su, {Chan Cheng} and Kuo, {Ting Shen}",

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AU - Wang, Tzu Li

AU - Su, Chan Cheng

AU - Kuo, Ting Shen

PY - 2008/8

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N2 - Because of the steric hindrance caused by the large bite angles of the employed dipropylenetriamine (dpt) ligand to the copper center, a five-coordinated copper triamine complex, [Cu(η3-dpt) (η2-dpt)](ClO4)2 (1), was prepared and structurally characterized. When water was added to a methanol solution of 1, the discrete mononuclear copper complex 1 was converted to a two-dimensional zigzag layer, and this conversion behavior was reversible as water was removed.

AB - Because of the steric hindrance caused by the large bite angles of the employed dipropylenetriamine (dpt) ligand to the copper center, a five-coordinated copper triamine complex, [Cu(η3-dpt) (η2-dpt)](ClO4)2 (1), was prepared and structurally characterized. When water was added to a methanol solution of 1, the discrete mononuclear copper complex 1 was converted to a two-dimensional zigzag layer, and this conversion behavior was reversible as water was removed.

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Structural interconversion controlled by hydrogen-bond interactions: A mononuclear copper triamine complex and a polynuclear copper triamine sheet

Abstract

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