Structural interconversion controlled by hydrogen-bond interactions: A mononuclear copper triamine complex and a polynuclear copper triamine sheet

Way-Zen Lee; Ya Lin Kang; Tzu Li Wang; Chan Cheng Su; Ting Shen Kuo

doi:10.1021/cg8002977

Structural interconversion controlled by hydrogen-bond interactions: A mononuclear copper triamine complex and a polynuclear copper triamine sheet

Way-Zen Lee, Ya Lin Kang, Tzu Li Wang, Chan Cheng Su, Ting Shen Kuo

Department of Chemistry

Research output: Contribution to journal › Article

15 Citations (Scopus)

Abstract

Because of the steric hindrance caused by the large bite angles of the employed dipropylenetriamine (dpt) ligand to the copper center, a five-coordinated copper triamine complex, [Cu(η³-dpt) (η²-dpt)](ClO₄)₂ (1), was prepared and structurally characterized. When water was added to a methanol solution of 1, the discrete mononuclear copper complex 1 was converted to a two-dimensional zigzag layer, and this conversion behavior was reversible as water was removed.

Original language	English
Pages (from-to)	2614-2616
Number of pages	3
Journal	Crystal Growth and Design
Volume	8
Issue number	8
DOIs	https://doi.org/10.1021/cg8002977
Publication status	Published - 2008 Aug 1

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ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

Cite this

Lee, W-Z., Kang, Y. L., Wang, T. L., Su, C. C., & Kuo, T. S. (2008). Structural interconversion controlled by hydrogen-bond interactions: A mononuclear copper triamine complex and a polynuclear copper triamine sheet. Crystal Growth and Design, 8(8), 2614-2616. https://doi.org/10.1021/cg8002977

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Access to Document

10.1021/cg8002977