Abstract
Because of the steric hindrance caused by the large bite angles of the employed dipropylenetriamine (dpt) ligand to the copper center, a five-coordinated copper triamine complex, [Cu(η3-dpt) (η2-dpt)](ClO4)2 (1), was prepared and structurally characterized. When water was added to a methanol solution of 1, the discrete mononuclear copper complex 1 was converted to a two-dimensional zigzag layer, and this conversion behavior was reversible as water was removed.
| Original language | English |
|---|---|
| Pages (from-to) | 2614-2616 |
| Number of pages | 3 |
| Journal | Crystal Growth and Design |
| Volume | 8 |
| Issue number | 8 |
| DOIs | |
| Publication status | Published - 2008 Aug 1 |
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ASJC Scopus subject areas
- Chemistry(all)
- Materials Science(all)
- Condensed Matter Physics
Cite this
Structural interconversion controlled by hydrogen-bond interactions : A mononuclear copper triamine complex and a polynuclear copper triamine sheet. / Lee, Way-Zen; Kang, Ya Lin; Wang, Tzu Li; Su, Chan Cheng; Kuo, Ting Shen.
In: Crystal Growth and Design, Vol. 8, No. 8, 01.08.2008, p. 2614-2616.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Structural interconversion controlled by hydrogen-bond interactions
T2 - A mononuclear copper triamine complex and a polynuclear copper triamine sheet
AU - Lee, Way-Zen
AU - Kang, Ya Lin
AU - Wang, Tzu Li
AU - Su, Chan Cheng
AU - Kuo, Ting Shen
PY - 2008/8/1
Y1 - 2008/8/1
N2 - Because of the steric hindrance caused by the large bite angles of the employed dipropylenetriamine (dpt) ligand to the copper center, a five-coordinated copper triamine complex, [Cu(η3-dpt) (η2-dpt)](ClO4)2 (1), was prepared and structurally characterized. When water was added to a methanol solution of 1, the discrete mononuclear copper complex 1 was converted to a two-dimensional zigzag layer, and this conversion behavior was reversible as water was removed.
AB - Because of the steric hindrance caused by the large bite angles of the employed dipropylenetriamine (dpt) ligand to the copper center, a five-coordinated copper triamine complex, [Cu(η3-dpt) (η2-dpt)](ClO4)2 (1), was prepared and structurally characterized. When water was added to a methanol solution of 1, the discrete mononuclear copper complex 1 was converted to a two-dimensional zigzag layer, and this conversion behavior was reversible as water was removed.
UR - http://www.scopus.com/inward/record.url?scp=61549134213&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=61549134213&partnerID=8YFLogxK
U2 - 10.1021/cg8002977
DO - 10.1021/cg8002977
M3 - Article
VL - 8
SP - 2614
EP - 2616
JO - Crystal Growth and Design
JF - Crystal Growth and Design
SN - 1528-7483
IS - 8
ER -