Structural identification of multidimensional metal–organic frameworks using soft x-ray tomography

Po Hsiang Tang; Pamela Berilyn So; Zi Jing Lin; Chia Chun Hsieh; Lee Jene Lai; Chia Her Lin

doi:10.1002/jccs.202300059

Structural identification of multidimensional metal–organic frameworks using soft x-ray tomography

Po Hsiang Tang, Pamela Berilyn So, Zi Jing Lin, Chia Chun Hsieh, Lee Jene Lai, Chia Her Lin^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

This paper mainly discusses the applicability of using soft x-ray tomography technology to examine the multidimensional structure of metal–organic frameworks, such as their core-shell and hollow framework, by visually observing their corresponding images in different energy bands by different excitation energies for different elements. The results show that the use of soft x-ray tomography (SXT) can effectively observe the distribution of metals in the structure, as well as observe the type of hollow pores the metal–organic framework (MOF) possesses. This pioneering evaluation of MOFs via SXT shows excellent performance in the structure identification of multidimensional metal–organic frameworks.

Original language	English
Journal	Journal of the Chinese Chemical Society
DOIs	https://doi.org/10.1002/jccs.202300059
Publication status	Accepted/In press - 2023

Keywords

metal distribution
metal–organic framework
soft x-ray tomography
structure identification

ASJC Scopus subject areas

Chemistry(all)

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10.1002/jccs.202300059

Cite this

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title = "Structural identification of multidimensional metal–organic frameworks using soft x-ray tomography",

abstract = "This paper mainly discusses the applicability of using soft x-ray tomography technology to examine the multidimensional structure of metal–organic frameworks, such as their core-shell and hollow framework, by visually observing their corresponding images in different energy bands by different excitation energies for different elements. The results show that the use of soft x-ray tomography (SXT) can effectively observe the distribution of metals in the structure, as well as observe the type of hollow pores the metal–organic framework (MOF) possesses. This pioneering evaluation of MOFs via SXT shows excellent performance in the structure identification of multidimensional metal–organic frameworks.",

keywords = "metal distribution, metal–organic framework, soft x-ray tomography, structure identification",

author = "Tang, {Po Hsiang} and So, {Pamela Berilyn} and Lin, {Zi Jing} and Hsieh, {Chia Chun} and Lai, {Lee Jene} and Lin, {Chia Her}",

note = "Funding Information: This work was supported by the National Science and Technology Council (NSTC) and the National Synchrotron Radiation Research Center (NSRRC), Taiwan, with Grant Nos. MOST 102‐3111‐M‐213‐002 and NSRRC 11233P24A, respectively. Publisher Copyright: {\textcopyright} 2023 The Chemical Society Located in Taipei & Wiley-VCH GmbH.",

year = "2023",

doi = "10.1002/jccs.202300059",

language = "English",

journal = "Journal of the Chinese Chemical Society",

issn = "0009-4536",

publisher = "Chinese Chemical Society",

}

TY - JOUR

T1 - Structural identification of multidimensional metal–organic frameworks using soft x-ray tomography

AU - Tang, Po Hsiang

AU - So, Pamela Berilyn

AU - Lin, Zi Jing

AU - Hsieh, Chia Chun

AU - Lai, Lee Jene

AU - Lin, Chia Her

N1 - Funding Information: This work was supported by the National Science and Technology Council (NSTC) and the National Synchrotron Radiation Research Center (NSRRC), Taiwan, with Grant Nos. MOST 102‐3111‐M‐213‐002 and NSRRC 11233P24A, respectively. Publisher Copyright: © 2023 The Chemical Society Located in Taipei & Wiley-VCH GmbH.

PY - 2023

Y1 - 2023

N2 - This paper mainly discusses the applicability of using soft x-ray tomography technology to examine the multidimensional structure of metal–organic frameworks, such as their core-shell and hollow framework, by visually observing their corresponding images in different energy bands by different excitation energies for different elements. The results show that the use of soft x-ray tomography (SXT) can effectively observe the distribution of metals in the structure, as well as observe the type of hollow pores the metal–organic framework (MOF) possesses. This pioneering evaluation of MOFs via SXT shows excellent performance in the structure identification of multidimensional metal–organic frameworks.

AB - This paper mainly discusses the applicability of using soft x-ray tomography technology to examine the multidimensional structure of metal–organic frameworks, such as their core-shell and hollow framework, by visually observing their corresponding images in different energy bands by different excitation energies for different elements. The results show that the use of soft x-ray tomography (SXT) can effectively observe the distribution of metals in the structure, as well as observe the type of hollow pores the metal–organic framework (MOF) possesses. This pioneering evaluation of MOFs via SXT shows excellent performance in the structure identification of multidimensional metal–organic frameworks.

KW - metal distribution

KW - metal–organic framework

KW - soft x-ray tomography

KW - structure identification

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DO - 10.1002/jccs.202300059

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JO - Journal of the Chinese Chemical Society

JF - Journal of the Chinese Chemical Society

ER -

Structural identification of multidimensional metal–organic frameworks using soft x-ray tomography

Abstract

Keywords

ASJC Scopus subject areas

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