Structural, electrical and magnetic characterization of the double perovskites Sr2CrMO6 (M = Mo, W): B′ 4d-5d system

T. S. Chan; R. S. Liu; G. Y. Guo; S. F. Hu; J. G. Lin; J. F. Lee; L. Y. Jang; C. R. Chang; C. Y. Huang

doi:10.1016/j.ssc.2004.05.050

Structural, electrical and magnetic characterization of the double perovskites Sr₂CrMO₆ (M = Mo, W): B′ 4d-5d system

T. S. Chan, R. S. Liu^*, G. Y. Guo, S. F. Hu, J. G. Lin, J. F. Lee, L. Y. Jang, C. R. Chang, C. Y. Huang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

20 Citations (Scopus)

Abstract

We report on the preparation and characterization of the variation of B′-site transition metal in Sr₂CrMO₆ (M = Mo, W) with double perovskites structure. The magnetic susceptibility shows that Sr₂CrMoO₆ and Sr₂CrWO₆ are antiferromagnets with T_N = 40 and 30 K at H = 1 T, respectively. In addition, a large magnetoresistance ratio (MR) of ∼ 38% (H = 3 T) at 5 K was observed in the Sr₂CrWO₆ compound. However, the Sr ₂CrMoO₆ compound does not show any significant MR even at high fields (MR ∼ 4%; H = 3 T and 5 K). The measured O K-edge X-ray absorption is in agreement with the calculated O p-density of states for both compounds.

Original language	English
Pages (from-to)	531-535
Number of pages	5
Journal	Solid State Communications
Volume	131
Issue number	8
DOIs	https://doi.org/10.1016/j.ssc.2004.05.050
Publication status	Published - 2004 Aug 1
Externally published	Yes

Keywords

A. Magnetically ordered materials
D. Magnetoresistance
E. X-ray spectroscopies

ASJC Scopus subject areas

Chemistry(all)
Condensed Matter Physics
Materials Chemistry

Access to Document

10.1016/j.ssc.2004.05.050

Cite this

@article{0d045ddba34b491aba4251b8b6326768,

title = "Structural, electrical and magnetic characterization of the double perovskites Sr2CrMO6 (M = Mo, W): B′ 4d-5d system",

abstract = "We report on the preparation and characterization of the variation of B′-site transition metal in Sr2CrMO6 (M = Mo, W) with double perovskites structure. The magnetic susceptibility shows that Sr2CrMoO6 and Sr2CrWO6 are antiferromagnets with TN = 40 and 30 K at H = 1 T, respectively. In addition, a large magnetoresistance ratio (MR) of ∼ 38% (H = 3 T) at 5 K was observed in the Sr2CrWO6 compound. However, the Sr 2CrMoO6 compound does not show any significant MR even at high fields (MR ∼ 4%; H = 3 T and 5 K). The measured O K-edge X-ray absorption is in agreement with the calculated O p-density of states for both compounds.",

keywords = "A. Magnetically ordered materials, D. Magnetoresistance, E. X-ray spectroscopies",

author = "Chan, {T. S.} and Liu, {R. S.} and Guo, {G. Y.} and Hu, {S. F.} and Lin, {J. G.} and Lee, {J. F.} and Jang, {L. Y.} and Chang, {C. R.} and Huang, {C. Y.}",

note = "Funding Information: We thank the financial supports form the National Science Council of Taiwan under the grant number 92-2113-M-002-036 and the Ministry Economic Affairs of Taiwan under the grand number 92-EC-17-A-08-S1-0006.",

year = "2004",

month = aug,

day = "1",

doi = "10.1016/j.ssc.2004.05.050",

language = "English",

volume = "131",

pages = "531--535",

journal = "Solid State Communications",

issn = "0038-1098",

publisher = "Elsevier Limited",

number = "8",

}

TY - JOUR

T1 - Structural, electrical and magnetic characterization of the double perovskites Sr2CrMO6 (M = Mo, W)

T2 - B′ 4d-5d system

AU - Chan, T. S.

AU - Liu, R. S.

AU - Guo, G. Y.

AU - Hu, S. F.

AU - Lin, J. G.

AU - Lee, J. F.

AU - Jang, L. Y.

AU - Chang, C. R.

AU - Huang, C. Y.

N1 - Funding Information: We thank the financial supports form the National Science Council of Taiwan under the grant number 92-2113-M-002-036 and the Ministry Economic Affairs of Taiwan under the grand number 92-EC-17-A-08-S1-0006.

PY - 2004/8/1

Y1 - 2004/8/1

N2 - We report on the preparation and characterization of the variation of B′-site transition metal in Sr2CrMO6 (M = Mo, W) with double perovskites structure. The magnetic susceptibility shows that Sr2CrMoO6 and Sr2CrWO6 are antiferromagnets with TN = 40 and 30 K at H = 1 T, respectively. In addition, a large magnetoresistance ratio (MR) of ∼ 38% (H = 3 T) at 5 K was observed in the Sr2CrWO6 compound. However, the Sr 2CrMoO6 compound does not show any significant MR even at high fields (MR ∼ 4%; H = 3 T and 5 K). The measured O K-edge X-ray absorption is in agreement with the calculated O p-density of states for both compounds.

AB - We report on the preparation and characterization of the variation of B′-site transition metal in Sr2CrMO6 (M = Mo, W) with double perovskites structure. The magnetic susceptibility shows that Sr2CrMoO6 and Sr2CrWO6 are antiferromagnets with TN = 40 and 30 K at H = 1 T, respectively. In addition, a large magnetoresistance ratio (MR) of ∼ 38% (H = 3 T) at 5 K was observed in the Sr2CrWO6 compound. However, the Sr 2CrMoO6 compound does not show any significant MR even at high fields (MR ∼ 4%; H = 3 T and 5 K). The measured O K-edge X-ray absorption is in agreement with the calculated O p-density of states for both compounds.

KW - A. Magnetically ordered materials

KW - D. Magnetoresistance

KW - E. X-ray spectroscopies

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DO - 10.1016/j.ssc.2004.05.050

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JO - Solid State Communications

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