Spinel Zinc Cobalt Oxide (ZnCo₂O₄) Porous Nanorods as a Cathode Material for Highly Durable Li-CO₂ Batteries

Li-CO₂ batteries are of great interest among researchers due to their high energy density and utilization of the greenhouse gas CO₂ to produce energy. However, several shortcomings have been encountered in the practical applications of Li-CO₂ batteries, among which their poor cyclability and high charge overpotential necessary to decompose the highly insulating discharge product (Li₂CO₃) are the most important. Herein, the spinel zinc cobalt oxide porous nanorods with carbon nanotubes (ZnCo₂O₄@CNTs) composite is employed as a cathode material in Li-CO₂ batteries to improve the latter's cycling performance. The ZnCo₂O₄@CNT cathode-based Li-CO₂ battery exhibited a full discharge capacity of 4275 mAh g^-1 and excellent cycling performance over 200 cycles with a charge overpotential below 4.3 V when operated at a current density of 100 mA g^-1 and fixed capacity of 500 mAh g^-1. The superior performance of the ZnCo₂O₄@CNT cathode composite was attributed to the synergistic effects of ZnCo₂O₄ and CNT. The highly porous ZnCo₂O₄ nanorod structures in the ZnCo₂O₄@CNT catalyst showed enhanced catalytic activity/stability, which effectively promoted CO₂ diffusion during the discharging process and accelerated Li₂CO₃ decomposition at a low charge overpotential.