Solvothermal syntheses and magnetic properties of two new coordination polymers with mixed ligands

Chia Her Lin; Tai Hsing Tsao

doi:10.1002/zaac.200800143

Solvothermal syntheses and magnetic properties of two new coordination polymers with mixed ligands

Chia Her Lin^*, Tai Hsing Tsao

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

Two new coordination polymers, [Ni(H₂O)(BDC)(bpp)]_n (1) and [Co(mBDC)(bpp)]_n (2) (BDC = 1,4-benzene dicarboxylate anion; bpp = 4,4′-trimethylene dipyridine; mBDC = 1,3-benzene dicarboxylate anion), were synthesized by solvothermal reaction and structurally characterized. Single crystal X-ray diffraction showed that 1 consists of an inclined interpenetration of 1D nets generating an overall 3D entanglement and compound 2 of 1D chains. The luminescent and magnetic properties of both compounds in the solid state were also investigated. Crystal data: 1: orthorhombic, Pnna; a = 18.3648(6), b = 13.6854(4), c = 16.2307(5) Å, V = 4079.3(2) Å³, and Z = 8. Crystal data: 2: triclinic, P1̄; a = 8.6966(4), b = 10.1093(4), c = 11.8334(4) Å, α = 68.263(1)°, β = 82.895(1)°, γ = 78.370(1)°, V = 945.16(7) Å³, and Z = 2.

Original language	English
Pages (from-to)	1759-1764
Number of pages	6
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	634
Issue number	10
DOIs	https://doi.org/10.1002/zaac.200800143
Publication status	Published - 2008 Aug
Externally published	Yes

Keywords

Cobalt
Crystal structure
Magnetism
Nickel
Solvothermal synthesis

ASJC Scopus subject areas

Inorganic Chemistry

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10.1002/zaac.200800143

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@article{8e55e53becd64506b511884ea2c81a27,

title = "Solvothermal syntheses and magnetic properties of two new coordination polymers with mixed ligands",

abstract = "Two new coordination polymers, [Ni(H2O)(BDC)(bpp)]n (1) and [Co(mBDC)(bpp)]n (2) (BDC = 1,4-benzene dicarboxylate anion; bpp = 4,4′-trimethylene dipyridine; mBDC = 1,3-benzene dicarboxylate anion), were synthesized by solvothermal reaction and structurally characterized. Single crystal X-ray diffraction showed that 1 consists of an inclined interpenetration of 1D nets generating an overall 3D entanglement and compound 2 of 1D chains. The luminescent and magnetic properties of both compounds in the solid state were also investigated. Crystal data: 1: orthorhombic, Pnna; a = 18.3648(6), b = 13.6854(4), c = 16.2307(5) {\AA}, V = 4079.3(2) {\AA}3, and Z = 8. Crystal data: 2: triclinic, P{\=1}; a = 8.6966(4), b = 10.1093(4), c = 11.8334(4) {\AA}, α = 68.263(1)°, β = 82.895(1)°, γ = 78.370(1)°, V = 945.16(7) {\AA}3, and Z = 2.",

keywords = "Cobalt, Crystal structure, Magnetism, Nickel, Solvothermal synthesis",

author = "Lin, {Chia Her} and Tsao, {Tai Hsing}",

year = "2008",

month = aug,

doi = "10.1002/zaac.200800143",

language = "English",

volume = "634",

pages = "1759--1764",

journal = "Zeitschrift fur Anorganische und Allgemeine Chemie",

issn = "0044-2313",

publisher = "Wiley-VCH Verlag",

number = "10",

}

TY - JOUR

T1 - Solvothermal syntheses and magnetic properties of two new coordination polymers with mixed ligands

AU - Lin, Chia Her

AU - Tsao, Tai Hsing

PY - 2008/8

Y1 - 2008/8

N2 - Two new coordination polymers, [Ni(H2O)(BDC)(bpp)]n (1) and [Co(mBDC)(bpp)]n (2) (BDC = 1,4-benzene dicarboxylate anion; bpp = 4,4′-trimethylene dipyridine; mBDC = 1,3-benzene dicarboxylate anion), were synthesized by solvothermal reaction and structurally characterized. Single crystal X-ray diffraction showed that 1 consists of an inclined interpenetration of 1D nets generating an overall 3D entanglement and compound 2 of 1D chains. The luminescent and magnetic properties of both compounds in the solid state were also investigated. Crystal data: 1: orthorhombic, Pnna; a = 18.3648(6), b = 13.6854(4), c = 16.2307(5) Å, V = 4079.3(2) Å3, and Z = 8. Crystal data: 2: triclinic, P1̄; a = 8.6966(4), b = 10.1093(4), c = 11.8334(4) Å, α = 68.263(1)°, β = 82.895(1)°, γ = 78.370(1)°, V = 945.16(7) Å3, and Z = 2.

AB - Two new coordination polymers, [Ni(H2O)(BDC)(bpp)]n (1) and [Co(mBDC)(bpp)]n (2) (BDC = 1,4-benzene dicarboxylate anion; bpp = 4,4′-trimethylene dipyridine; mBDC = 1,3-benzene dicarboxylate anion), were synthesized by solvothermal reaction and structurally characterized. Single crystal X-ray diffraction showed that 1 consists of an inclined interpenetration of 1D nets generating an overall 3D entanglement and compound 2 of 1D chains. The luminescent and magnetic properties of both compounds in the solid state were also investigated. Crystal data: 1: orthorhombic, Pnna; a = 18.3648(6), b = 13.6854(4), c = 16.2307(5) Å, V = 4079.3(2) Å3, and Z = 8. Crystal data: 2: triclinic, P1̄; a = 8.6966(4), b = 10.1093(4), c = 11.8334(4) Å, α = 68.263(1)°, β = 82.895(1)°, γ = 78.370(1)°, V = 945.16(7) Å3, and Z = 2.

KW - Cobalt

KW - Crystal structure

KW - Magnetism

KW - Nickel

KW - Solvothermal synthesis

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SN - 0044-2313

VL - 634

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EP - 1764

JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

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ER -

Solvothermal syntheses and magnetic properties of two new coordination polymers with mixed ligands

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Keywords

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