Small Molecule Reactions on Clean and Modified Iron Surfaces

S. L. Bernasek; J. P. Lu; M. R. Albert; W. S. Hung

doi:10.1016/S0167-2991(08)61949-7

Small Molecule Reactions on Clean and Modified Iron Surfaces

S. L. Bernasek
, J. P. Lu
, M. R. Albert
, W. S. Hung

Research output: Contribution to journal › Article › peer-review

Abstract

The connection between structure and reactivity in heterogeneous reactions can be best studied using model substrates whose structure can be characterized and controlled. Several examples of this approach to the understanding of structure-reactivity relationships in heterogeneous catalysis are presented, based on recent investigations of the Fe(100) surface. This surface exhibits a rich and complex chemistry, illustrated here by discussions of the adsorption and reaction of CO, O₂, H₂O, CH₃OH and CH₃SH on the clean and modified Fe(100) surface. An approach to the preparation of characterizable mixed metal oxide substrates based on the hydroxylated Fe(100) surface is also presented.

Original language	English
Pages (from-to)	315-326
Number of pages	12
Journal	Studies in Surface Science and Catalysis
Volume	67
Issue number	C
DOIs	https://doi.org/10.1016/S0167-2991(08)61949-7
Publication status	Published - 1991 Jan 1
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Condensed Matter Physics
Physical and Theoretical Chemistry
Surfaces, Coatings and Films
Materials Chemistry

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10.1016/S0167-2991(08)61949-7

Cite this

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title = "Small Molecule Reactions on Clean and Modified Iron Surfaces",

abstract = "The connection between structure and reactivity in heterogeneous reactions can be best studied using model substrates whose structure can be characterized and controlled. Several examples of this approach to the understanding of structure-reactivity relationships in heterogeneous catalysis are presented, based on recent investigations of the Fe(100) surface. This surface exhibits a rich and complex chemistry, illustrated here by discussions of the adsorption and reaction of CO, O2, H2O, CH3OH and CH3SH on the clean and modified Fe(100) surface. An approach to the preparation of characterizable mixed metal oxide substrates based on the hydroxylated Fe(100) surface is also presented.",

author = "Bernasek, \{S. L.\} and Lu, \{J. P.\} and Albert, \{M. R.\} and Hung, \{W. S.\}",

note = "Funding Information: ACKNOWLEDGEMENTS This work was supported by the National Science Foundation, Division of Materials Research, and in its early stages by grants from Exxon Research and Engineering. Collaboration and discussion with Dr. John Gland and Dr. Dan Dwyer formerly at Exxon Research and Engineering, and with Professor Jeffrey Schwartz of Princeton University are gratefully acknowledged.",

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doi = "10.1016/S0167-2991(08)61949-7",

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AU - Bernasek, S. L.

AU - Lu, J. P.

AU - Albert, M. R.

AU - Hung, W. S.

N1 - Funding Information: ACKNOWLEDGEMENTS This work was supported by the National Science Foundation, Division of Materials Research, and in its early stages by grants from Exxon Research and Engineering. Collaboration and discussion with Dr. John Gland and Dr. Dan Dwyer formerly at Exxon Research and Engineering, and with Professor Jeffrey Schwartz of Princeton University are gratefully acknowledged.

PY - 1991/1/1

Y1 - 1991/1/1

N2 - The connection between structure and reactivity in heterogeneous reactions can be best studied using model substrates whose structure can be characterized and controlled. Several examples of this approach to the understanding of structure-reactivity relationships in heterogeneous catalysis are presented, based on recent investigations of the Fe(100) surface. This surface exhibits a rich and complex chemistry, illustrated here by discussions of the adsorption and reaction of CO, O2, H2O, CH3OH and CH3SH on the clean and modified Fe(100) surface. An approach to the preparation of characterizable mixed metal oxide substrates based on the hydroxylated Fe(100) surface is also presented.

AB - The connection between structure and reactivity in heterogeneous reactions can be best studied using model substrates whose structure can be characterized and controlled. Several examples of this approach to the understanding of structure-reactivity relationships in heterogeneous catalysis are presented, based on recent investigations of the Fe(100) surface. This surface exhibits a rich and complex chemistry, illustrated here by discussions of the adsorption and reaction of CO, O2, H2O, CH3OH and CH3SH on the clean and modified Fe(100) surface. An approach to the preparation of characterizable mixed metal oxide substrates based on the hydroxylated Fe(100) surface is also presented.

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JO - Studies in Surface Science and Catalysis

JF - Studies in Surface Science and Catalysis

IS - C

ER -

Small Molecule Reactions on Clean and Modified Iron Surfaces

Abstract

ASJC Scopus subject areas

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