Abstract
Highly emissive conjugated compounds containing pyridine (or pyrimidine) and cyano ligands have been synthesized by palladium-catalyzed cross-coupling reaction. These ligands readily react with Re(CO)3(THF)2Br to form cyclic supramolecules by self-assembly processes. At room temperature these supramolecules are emissive, and the emission is ligand-localized, as evidenced from the Stokes shift and the lifetime data.
Original language | English |
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Pages (from-to) | 975-982 |
Number of pages | 8 |
Journal | Journal of Organometallic Chemistry |
Volume | 691 |
Issue number | 5 |
DOIs | |
Publication status | Published - 2006 Feb 15 |
Keywords
- Rhenium
- Self-assembly
- Supramolecule
ASJC Scopus subject areas
- Biochemistry
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
- Materials Chemistry