Self-assembly molecular architectures with novel cyclic dimers

Ping Hsin Huang, Jiann T. Lin, Ming Chang P. Yeh

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

Highly emissive conjugated compounds containing pyridine (or pyrimidine) and cyano ligands have been synthesized by palladium-catalyzed cross-coupling reaction. These ligands readily react with Re(CO)3(THF)2Br to form cyclic supramolecules by self-assembly processes. At room temperature these supramolecules are emissive, and the emission is ligand-localized, as evidenced from the Stokes shift and the lifetime data.

Original languageEnglish
Pages (from-to)975-982
Number of pages8
JournalJournal of Organometallic Chemistry
Volume691
Issue number5
DOIs
Publication statusPublished - 2006 Feb 15

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Keywords

  • Rhenium
  • Self-assembly
  • Supramolecule

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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