Self-assembly molecular architectures with novel cyclic dimers

Ping Hsin Huang, Jiann T. Lin, Ming-Chang P. Yeh

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

Highly emissive conjugated compounds containing pyridine (or pyrimidine) and cyano ligands have been synthesized by palladium-catalyzed cross-coupling reaction. These ligands readily react with Re(CO)3(THF)2Br to form cyclic supramolecules by self-assembly processes. At room temperature these supramolecules are emissive, and the emission is ligand-localized, as evidenced from the Stokes shift and the lifetime data.

Original languageEnglish
Pages (from-to)975-982
Number of pages8
JournalJournal of Organometallic Chemistry
Volume691
Issue number5
DOIs
Publication statusPublished - 2006 Feb 15

Fingerprint

Dimers
Self assembly
self assembly
Ligands
dimers
ligands
cross coupling
Cross Reactions
Palladium
pyrimidines
Carbon Monoxide
palladium
life (durability)
Temperature
shift
room temperature
pyrimidine

Keywords

  • Rhenium
  • Self-assembly
  • Supramolecule

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

Self-assembly molecular architectures with novel cyclic dimers. / Huang, Ping Hsin; Lin, Jiann T.; Yeh, Ming-Chang P.

In: Journal of Organometallic Chemistry, Vol. 691, No. 5, 15.02.2006, p. 975-982.

Research output: Contribution to journalArticle

Huang, Ping Hsin ; Lin, Jiann T. ; Yeh, Ming-Chang P. / Self-assembly molecular architectures with novel cyclic dimers. In: Journal of Organometallic Chemistry. 2006 ; Vol. 691, No. 5. pp. 975-982.
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