Self-adaptation of manganese-chloride arrangement toward high spin Mn 5(μ-Cl) 4 cluster-based metal-organic framework with S = 15/ 2

Shao Hsuan Lin; Chen I. Yang; Ting Shen Kuo; Ming Hsi Chiang; Kung Chung Hsu; Kuang Lieh Lu

doi:10.1039/c2dt11760f

Self-adaptation of manganese-chloride arrangement toward high spin Mn ₅(μ-Cl) ₄ cluster-based metal-organic framework with S = ¹⁵/ ₂

Shao Hsuan Lin, Chen I. Yang, Ting Shen Kuo, Ming Hsi Chiang, Kung Chung Hsu, Kuang Lieh Lu^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

The self-adaptation of manganese-chloride arrangement with the tripodal ligand 1,3,5-tris(benzimidazoyl-1-ylmethyl)-2,4,6-trimethylbenzene (Me ₃-TBzIm) afforded a rare 3D metal-organic framework, [Mn ₅Cl ₁₀(Me ₃-TBzIm) ₄] _n (1) showing a high spin ground state with S = ¹⁵/ ₂.

Original language	English
Pages (from-to)	1448-1450
Number of pages	3
Journal	Dalton Transactions
Volume	41
Issue number	5
DOIs	https://doi.org/10.1039/c2dt11760f
Publication status	Published - 2012 Feb 7

ASJC Scopus subject areas

Inorganic Chemistry

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10.1039/c2dt11760f

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title = "Self-adaptation of manganese-chloride arrangement toward high spin Mn 5(μ-Cl) 4 cluster-based metal-organic framework with S = 15/ 2 ",

abstract = "The self-adaptation of manganese-chloride arrangement with the tripodal ligand 1,3,5-tris(benzimidazoyl-1-ylmethyl)-2,4,6-trimethylbenzene (Me 3-TBzIm) afforded a rare 3D metal-organic framework, [Mn 5Cl 10(Me 3-TBzIm) 4] n (1) showing a high spin ground state with S = 15/ 2.",

author = "Lin, {Shao Hsuan} and Yang, {Chen I.} and Kuo, {Ting Shen} and Chiang, {Ming Hsi} and Hsu, {Kung Chung} and Lu, {Kuang Lieh}",

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doi = "10.1039/c2dt11760f",

language = "English",

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pages = "1448--1450",

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publisher = "Royal Society of Chemistry",

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T1 - Self-adaptation of manganese-chloride arrangement toward high spin Mn 5(μ-Cl) 4 cluster-based metal-organic framework with S = 15/ 2

AU - Lin, Shao Hsuan

AU - Yang, Chen I.

AU - Kuo, Ting Shen

AU - Chiang, Ming Hsi

AU - Hsu, Kung Chung

AU - Lu, Kuang Lieh

PY - 2012/2/7

Y1 - 2012/2/7

N2 - The self-adaptation of manganese-chloride arrangement with the tripodal ligand 1,3,5-tris(benzimidazoyl-1-ylmethyl)-2,4,6-trimethylbenzene (Me 3-TBzIm) afforded a rare 3D metal-organic framework, [Mn 5Cl 10(Me 3-TBzIm) 4] n (1) showing a high spin ground state with S = 15/ 2.

AB - The self-adaptation of manganese-chloride arrangement with the tripodal ligand 1,3,5-tris(benzimidazoyl-1-ylmethyl)-2,4,6-trimethylbenzene (Me 3-TBzIm) afforded a rare 3D metal-organic framework, [Mn 5Cl 10(Me 3-TBzIm) 4] n (1) showing a high spin ground state with S = 15/ 2.

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U2 - 10.1039/c2dt11760f

DO - 10.1039/c2dt11760f

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VL - 41

SP - 1448

EP - 1450

JO - Dalton Transactions

JF - Dalton Transactions

IS - 5

ER -

Self-adaptation of manganese-chloride arrangement toward high spin Mn ₅(μ-Cl) ₄ cluster-based metal-organic framework with S = ¹⁵/ ₂

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CCDC 830809: Experimental Crystal Structure Determination

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Self-adaptation of manganese-chloride arrangement toward high spin Mn 5(μ-Cl) 4 cluster-based metal-organic framework with S = 15/ 2

Abstract

ASJC Scopus subject areas

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CCDC 830809: Experimental Crystal Structure Determination

Cite this

Self-adaptation of manganese-chloride arrangement toward high spin Mn ₅(μ-Cl) ₄ cluster-based metal-organic framework with S = ¹⁵/ ₂