Self-adaptation of manganese-chloride arrangement toward high spin Mn 5(μ-Cl) 4 cluster-based metal-organic framework with S = 15/ 2

Shao Hsuan Lin, Chen I. Yang, Ting Shen Kuo, Ming Hsi Chiang, Kung Chung Hsu, Kuang Lieh Lu

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Abstract

The self-adaptation of manganese-chloride arrangement with the tripodal ligand 1,3,5-tris(benzimidazoyl-1-ylmethyl)-2,4,6-trimethylbenzene (Me 3-TBzIm) afforded a rare 3D metal-organic framework, [Mn 5Cl 10(Me 3-TBzIm) 4] n (1) showing a high spin ground state with S = 15/ 2.

Original languageEnglish
Pages (from-to)1448-1450
Number of pages3
JournalDalton Transactions
Volume41
Issue number5
DOIs
Publication statusPublished - 2012 Feb 7

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ASJC Scopus subject areas

  • Inorganic Chemistry

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