Self-adaptation of manganese-chloride arrangement toward high spin Mn 5(μ-Cl) 4 cluster-based metal-organic framework with S = 15/ 2

Shao Hsuan Lin; Chen I. Yang; Ting Shen Kuo; Ming Hsi Chiang; Kung Chung Hsu; Kuang Lieh Lu

doi:10.1039/c2dt11760f

Self-adaptation of manganese-chloride arrangement toward high spin Mn ₅(μ-Cl) ₄ cluster-based metal-organic framework with S = ¹⁵/ ₂

Shao Hsuan Lin, Chen I. Yang, Ting Shen Kuo, Ming Hsi Chiang, Kung Chung Hsu, Kuang Lieh Lu

Department of Chemistry

Research output: Contribution to journal › Article

9 Citations (Scopus)

Abstract

The self-adaptation of manganese-chloride arrangement with the tripodal ligand 1,3,5-tris(benzimidazoyl-1-ylmethyl)-2,4,6-trimethylbenzene (Me ₃-TBzIm) afforded a rare 3D metal-organic framework, [Mn ₅Cl ₁₀(Me ₃-TBzIm) ₄] _n (1) showing a high spin ground state with S = ¹⁵/ ₂.

Original language	English
Pages (from-to)	1448-1450
Number of pages	3
Journal	Dalton Transactions
Volume	41
Issue number	5
DOIs	https://doi.org/10.1039/c2dt11760f
Publication status	Published - 2012 Feb 7

ASJC Scopus subject areas

Inorganic Chemistry

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Lin, S. H., Yang, C. I., Kuo, T. S., Chiang, M. H., Hsu, K. C., & Lu, K. L. (2012). Self-adaptation of manganese-chloride arrangement toward high spin Mn ₅(μ-Cl) ₄ cluster-based metal-organic framework with S = ¹⁵/ ₂ Dalton Transactions, 41(5), 1448-1450. https://doi.org/10.1039/c2dt11760f

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abstract = "The self-adaptation of manganese-chloride arrangement with the tripodal ligand 1,3,5-tris(benzimidazoyl-1-ylmethyl)-2,4,6-trimethylbenzene (Me 3-TBzIm) afforded a rare 3D metal-organic framework, [Mn 5Cl 10(Me 3-TBzIm) 4] n (1) showing a high spin ground state with S = 15/ 2.",

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AU - Kuo, Ting Shen

AU - Chiang, Ming Hsi

AU - Hsu, Kung Chung

AU - Lu, Kuang Lieh

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