Rhodium(I)-catalyzed intramolecular cyclohexadienyl Pauson-Khand reaction: Facile approach to tricarbocycles

Ming Chang P. Yeh; Wen Cheng Tsao; Jin Shen Ho; Chih Chuan Tai; Dai Yu Chiou; Ling Hsien Tu

doi:10.1021/om030634p

Rhodium(I)-catalyzed intramolecular cyclohexadienyl Pauson-Khand reaction: Facile approach to tricarbocycles

Ming Chang P. Yeh^*
, Wen Cheng Tsao
, Jin Shen Ho
, Chih Chuan Tai
, Dai Yu Chiou
, Ling Hsien Tu

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

The rhodium-catalyzed Pauson - Khand reaction (PKR) of cyclohexa-l,3-dienes containing two methylene carbons and an alkyne in a chain produced regular PKR products. Cyclohexadienynes bearing three methylene units and a aromatic ring at the alkyne afforded regular PKR products and angularly fused tricyclic compounds, which were derived from diene migration followed by the PKR process.

Original language	English
Pages (from-to)	792-799
Number of pages	8
Journal	Organometallics
Volume	23
Issue number	4
DOIs	https://doi.org/10.1021/om030634p
Publication status	Published - 2004 Feb 16

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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abstract = "The rhodium-catalyzed Pauson - Khand reaction (PKR) of cyclohexa-l,3-dienes containing two methylene carbons and an alkyne in a chain produced regular PKR products. Cyclohexadienynes bearing three methylene units and a aromatic ring at the alkyne afforded regular PKR products and angularly fused tricyclic compounds, which were derived from diene migration followed by the PKR process.",

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AU - Yeh, Ming Chang P.

AU - Tsao, Wen Cheng

AU - Ho, Jin Shen

AU - Tai, Chih Chuan

AU - Chiou, Dai Yu

AU - Tu, Ling Hsien

PY - 2004/2/16

Y1 - 2004/2/16

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AB - The rhodium-catalyzed Pauson - Khand reaction (PKR) of cyclohexa-l,3-dienes containing two methylene carbons and an alkyne in a chain produced regular PKR products. Cyclohexadienynes bearing three methylene units and a aromatic ring at the alkyne afforded regular PKR products and angularly fused tricyclic compounds, which were derived from diene migration followed by the PKR process.

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UR - https://www.scopus.com/pages/publications/1442309763#tab=citedBy

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Rhodium(I)-catalyzed intramolecular cyclohexadienyl Pauson-Khand reaction: Facile approach to tricarbocycles

Abstract

ASJC Scopus subject areas

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