Rhodium(I)-catalyzed intramolecular cyclohexadienyl Pauson-Khand reaction: Facile approach to tricarbocycles

Ming Chang P. Yeh, Wen Cheng Tsao, Jin Shen Ho, Chih Chuan Tai, Dai Yu Chiou, Ling Hsien Tu

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

The rhodium-catalyzed Pauson - Khand reaction (PKR) of cyclohexa-l,3-dienes containing two methylene carbons and an alkyne in a chain produced regular PKR products. Cyclohexadienynes bearing three methylene units and a aromatic ring at the alkyne afforded regular PKR products and angularly fused tricyclic compounds, which were derived from diene migration followed by the PKR process.

Original languageEnglish
Pages (from-to)792-799
Number of pages8
JournalOrganometallics
Volume23
Issue number4
DOIs
Publication statusPublished - 2004 Feb 16

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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