Rhodium(I)-catalyzed intramolecular cyclohexadienyl Pauson-Khand reaction: Facile approach to tricarbocycles

Ming-Chang P. Yeh, Wen Cheng Tsao, Jin Shen Ho, Chih Chuan Tai, Dai Yu Chiou, Ling-Hsien Tu

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

The rhodium-catalyzed Pauson - Khand reaction (PKR) of cyclohexa-l,3-dienes containing two methylene carbons and an alkyne in a chain produced regular PKR products. Cyclohexadienynes bearing three methylene units and a aromatic ring at the alkyne afforded regular PKR products and angularly fused tricyclic compounds, which were derived from diene migration followed by the PKR process.

Original languageEnglish
Pages (from-to)792-799
Number of pages8
JournalOrganometallics
Volume23
Issue number4
DOIs
Publication statusPublished - 2004 Feb 16

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Rhodium
Alkynes
dienes
alkynes
rhodium
Reaction products
methylene
reaction products
Bearings (structural)
Carbon
carbon
rings

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

Cite this

Rhodium(I)-catalyzed intramolecular cyclohexadienyl Pauson-Khand reaction : Facile approach to tricarbocycles. / Yeh, Ming-Chang P.; Tsao, Wen Cheng; Ho, Jin Shen; Tai, Chih Chuan; Chiou, Dai Yu; Tu, Ling-Hsien.

In: Organometallics, Vol. 23, No. 4, 16.02.2004, p. 792-799.

Research output: Contribution to journalArticle

Yeh, Ming-Chang P. ; Tsao, Wen Cheng ; Ho, Jin Shen ; Tai, Chih Chuan ; Chiou, Dai Yu ; Tu, Ling-Hsien. / Rhodium(I)-catalyzed intramolecular cyclohexadienyl Pauson-Khand reaction : Facile approach to tricarbocycles. In: Organometallics. 2004 ; Vol. 23, No. 4. pp. 792-799.
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