Regioselective formation of allylidenecyclopropanes from Fischer chromiumcarbene complexes and vinylidenecyclopropanes

Hwu Chong-Cheng*, Wang Fu-Chun, P. Yeh Ming-Chang, Sheu Jyh-Horng

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

25 Citations (Scopus)

Abstract

The reaction of Fischer chromiumcarbene complexes with vinylidenecyclopropanes in refluxing benzene proceeds in a highly regioselective fashion to afford allylidenecyclopropanes.

Original languageEnglish
Pages (from-to)123-128
Number of pages6
JournalJournal of Organometallic Chemistry
Volume474
Issue number1-2
DOIs
Publication statusPublished - 1994 Jul 12

Keywords

  • Carbene
  • Chromium
  • Infrared spectroscopy
  • Mass spectrometry
  • Molybdenum
  • Nuclear magnetic resonance
  • Small ring

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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