TY - JOUR
T1 - Reactions of (η3-allyl)tetracarbonyliron cations with the highly functionalized copper reagents RCu(CN)Znl
AU - Yeh, Ming Chang P.
AU - Tau, Sheng I.
PY - 1992
Y1 - 1992
N2 - The addition of the highly functionalized copper reagents RCu(CN)Znl to (η3-allyl)Fe(CO)4 cations occurs mainly at the unsubstituted allyl terminus to yield the functionalized isoprenyl derivatives; with substituents on both ends of the allyl, the regular isoprenyl adducts are isolated together with ketone products which are derived from nucleophilic additions to the carbon monoxide ligands.
AB - The addition of the highly functionalized copper reagents RCu(CN)Znl to (η3-allyl)Fe(CO)4 cations occurs mainly at the unsubstituted allyl terminus to yield the functionalized isoprenyl derivatives; with substituents on both ends of the allyl, the regular isoprenyl adducts are isolated together with ketone products which are derived from nucleophilic additions to the carbon monoxide ligands.
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U2 - 10.1039/C39920000013
DO - 10.1039/C39920000013
M3 - Article
AN - SCOPUS:0039800161
SN - 0022-4936
SP - 13
EP - 15
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 1
ER -