The addition of the highly functionalized copper reagents RCu(CN)Znl to (η3-allyl)Fe(CO)4 cations occurs mainly at the unsubstituted allyl terminus to yield the functionalized isoprenyl derivatives; with substituents on both ends of the allyl, the regular isoprenyl adducts are isolated together with ketone products which are derived from nucleophilic additions to the carbon monoxide ligands.
|Number of pages||3|
|Journal||Journal of the Chemical Society, Chemical Communications|
|Publication status||Published - 1992|
ASJC Scopus subject areas
- Molecular Medicine