Reactions of (η3-allyl)tetracarbonyliron cations with the highly functionalized copper reagents RCu(CN)Znl

Ming Chang P. Yeh, Sheng I. Tau

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

The addition of the highly functionalized copper reagents RCu(CN)Znl to (η3-allyl)Fe(CO)4 cations occurs mainly at the unsubstituted allyl terminus to yield the functionalized isoprenyl derivatives; with substituents on both ends of the allyl, the regular isoprenyl adducts are isolated together with ketone products which are derived from nucleophilic additions to the carbon monoxide ligands.

Original languageEnglish
Pages (from-to)13-15
Number of pages3
JournalJournal of the Chemical Society, Chemical Communications
Issue number1
DOIs
Publication statusPublished - 1992 Dec 1

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Carbon Monoxide
Ketones
Carbon monoxide
Cations
Copper
Positive ions
Ligands
Derivatives
ferryl iron

ASJC Scopus subject areas

  • Molecular Medicine

Cite this

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abstract = "The addition of the highly functionalized copper reagents RCu(CN)Znl to (η3-allyl)Fe(CO)4 cations occurs mainly at the unsubstituted allyl terminus to yield the functionalized isoprenyl derivatives; with substituents on both ends of the allyl, the regular isoprenyl adducts are isolated together with ketone products which are derived from nucleophilic additions to the carbon monoxide ligands.",
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