Reaction of Tricarbonyl(η3‐allyl)iron(0) Anions with Bromine

Ming‐Chang P. Yeh; Kuo‐Ping ‐P Kang; Chong‐Chen ‐C Hwu

doi:10.1002/jccs.199100079

Reaction of Tricarbonyl(η³‐allyl)iron(0) Anions with Bromine

Ming‐Chang P. Yeh^*, Kuo‐Ping ‐P Kang, Chong‐Chen ‐C Hwu

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

The addition of reactive carbanions to tricarbonyl(η⁴‐1,3‐diene)iron(0) complexes proceeded at 23°C to give putative tricarbonyl(η³‐allyl)iron(0) anion complexes. Trapping of the reactive intermediates with bromine produced nucleophilic‐substituted tricarbonyl(η⁴‐1,3‐diene)iron(0) complexes.

Original language	English
Pages (from-to)	475-482
Number of pages	8
Journal	Journal of the Chinese Chemical Society
Volume	38
Issue number	5
DOIs	https://doi.org/10.1002/jccs.199100079
Publication status	Published - 1991 Oct

Keywords

(η‐Allyl) syn/anti isomerization
Reductive elimination
Tricarbonyl(η‐allyl)iron(0) anionic complexes
β‐Hydride elimination

ASJC Scopus subject areas

General Chemistry

Access to Document

10.1002/jccs.199100079

Cite this

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title = "Reaction of Tricarbonyl(η3‐allyl)iron(0) Anions with Bromine",

abstract = "The addition of reactive carbanions to tricarbonyl(η4‐1,3‐diene)iron(0) complexes proceeded at 23°C to give putative tricarbonyl(η3‐allyl)iron(0) anion complexes. Trapping of the reactive intermediates with bromine produced nucleophilic‐substituted tricarbonyl(η4‐1,3‐diene)iron(0) complexes.",

keywords = "(η‐Allyl) syn/anti isomerization, Reductive elimination, Tricarbonyl(η‐allyl)iron(0) anionic complexes, β‐Hydride elimination",

author = "Yeh, {Ming‐Chang P.} and Kang, {Kuo‐Ping ‐P} and Hwu, {Chong‐Chen ‐C}",

year = "1991",

month = oct,

doi = "10.1002/jccs.199100079",

language = "English",

volume = "38",

pages = "475--482",

journal = "Journal of the Chinese Chemical Society",

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T1 - Reaction of Tricarbonyl(η3‐allyl)iron(0) Anions with Bromine

AU - Yeh, Ming‐Chang P.

AU - Kang, Kuo‐Ping ‐P

AU - Hwu, Chong‐Chen ‐C

PY - 1991/10

Y1 - 1991/10

N2 - The addition of reactive carbanions to tricarbonyl(η4‐1,3‐diene)iron(0) complexes proceeded at 23°C to give putative tricarbonyl(η3‐allyl)iron(0) anion complexes. Trapping of the reactive intermediates with bromine produced nucleophilic‐substituted tricarbonyl(η4‐1,3‐diene)iron(0) complexes.

AB - The addition of reactive carbanions to tricarbonyl(η4‐1,3‐diene)iron(0) complexes proceeded at 23°C to give putative tricarbonyl(η3‐allyl)iron(0) anion complexes. Trapping of the reactive intermediates with bromine produced nucleophilic‐substituted tricarbonyl(η4‐1,3‐diene)iron(0) complexes.

KW - (η‐Allyl) syn/anti isomerization

KW - Reductive elimination

KW - Tricarbonyl(η‐allyl)iron(0) anionic complexes

KW - β‐Hydride elimination

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