Radical reactions in esters with alkoxy functionality chemistry an unusual alcohol moiety hydrogen abstraction

Ming Chung Yan, Yeong Jiunn Jang, Jhenyi Wu, Yung Feng Lin, Ching Fa Yao

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

Various geometrically pure (E)-alkenes have been synthesized by radical substitution of alcohol moieties generated via hydrogen abstraction within ethyl esters. These reactions occurred with high regioselectivity and gave a new access to 1-methyl-3-aryl-allyl esters.

Original languageEnglish
Pages (from-to)3685-3687
Number of pages3
JournalTetrahedron Letters
Volume45
Issue number18
DOIs
Publication statusPublished - 2004 Apr 26

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Hydrogen
Esters
Alcohols
Regioselectivity
Alkenes
Substitution reactions
alkoxyl radical

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Cite this

Radical reactions in esters with alkoxy functionality chemistry an unusual alcohol moiety hydrogen abstraction. / Yan, Ming Chung; Jang, Yeong Jiunn; Wu, Jhenyi; Lin, Yung Feng; Yao, Ching Fa.

In: Tetrahedron Letters, Vol. 45, No. 18, 26.04.2004, p. 3685-3687.

Research output: Contribution to journalArticle

Yan, Ming Chung ; Jang, Yeong Jiunn ; Wu, Jhenyi ; Lin, Yung Feng ; Yao, Ching Fa. / Radical reactions in esters with alkoxy functionality chemistry an unusual alcohol moiety hydrogen abstraction. In: Tetrahedron Letters. 2004 ; Vol. 45, No. 18. pp. 3685-3687.
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