Promotion of Ternary Pt-Sn-Ag Catalysts toward Ethanol Oxidation Reaction: Revealing Electronic and Structural Effects of Additive Metals

Sheng Dai, Tzu Hsi Huang, Xingxu Yan, Chao Yu Yang, Tsan Yao Chen, Jeng Han Wang, Xiaoqing Pan, Kuan Wen Wang

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

The use of a computation-guided method and the discovered structure-property relationship would establish a rational strategy to aid the development of ethanol oxidation reaction (EOR) catalysts for possible commercialization of direct ethanol fuel cells. Here, we investigate the promotion roles of additive metals in ternary Pt-Sn-Ag catalysts toward EOR via a combination of density functional theory calculation and experimental evidence. By calculating the EOR energetics, the promotion roles of Sn and Ag were revealed from the viewpoints of electronic and structural effects, respectively: (1) The addition of Sn and Ag on Pt essentially reduce the reaction energy and activation barrier of the second two-electron transfer process of EOR, facilitating the oxidation of acetaldehyde to acetic acid; (2) a homogeneous Pt-Sn-Ag surface configuration strengthens the adsorption energy of ethanol, thus improving the activity for ethanol oxidizing to acetaldehyde. Experimentally, various Pt-Sn-Ag nanorod catalysts with different surface configurations were synthesized, and their electrochemical performances demonstrate the two EOR promotion effects as predicted. Notably, our extended Pt6-Sn-Ag nanorod catalyst shows remarkably enhanced EOR activity and stability, highlighting a homogeneous Pt-Sn-Ag surface configuration as an optimal structure for EOR catalysts.

Original languageEnglish
Pages (from-to)2550-2557
Number of pages8
JournalACS Energy Letters
Volume3
Issue number10
DOIs
Publication statusPublished - 2018 Oct 12

Fingerprint

Ethanol
Metals
Oxidation
Catalysts
Acetaldehyde
Nanorods
Direct ethanol fuel cells (DEFC)
Acetic acid
Acetic Acid
Density functional theory
Chemical activation
Adsorption
Electrons

ASJC Scopus subject areas

  • Chemistry (miscellaneous)
  • Renewable Energy, Sustainability and the Environment
  • Fuel Technology
  • Energy Engineering and Power Technology
  • Materials Chemistry

Cite this

Promotion of Ternary Pt-Sn-Ag Catalysts toward Ethanol Oxidation Reaction : Revealing Electronic and Structural Effects of Additive Metals. / Dai, Sheng; Huang, Tzu Hsi; Yan, Xingxu; Yang, Chao Yu; Chen, Tsan Yao; Wang, Jeng Han; Pan, Xiaoqing; Wang, Kuan Wen.

In: ACS Energy Letters, Vol. 3, No. 10, 12.10.2018, p. 2550-2557.

Research output: Contribution to journalArticle

Dai, Sheng ; Huang, Tzu Hsi ; Yan, Xingxu ; Yang, Chao Yu ; Chen, Tsan Yao ; Wang, Jeng Han ; Pan, Xiaoqing ; Wang, Kuan Wen. / Promotion of Ternary Pt-Sn-Ag Catalysts toward Ethanol Oxidation Reaction : Revealing Electronic and Structural Effects of Additive Metals. In: ACS Energy Letters. 2018 ; Vol. 3, No. 10. pp. 2550-2557.
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