Poly[bis-(2-4,4′-bipyridine)bis-(3-nitro-benzoato) cobalt(II)]

Pei Hsuan Chiang, Shih Chen Hsu, Chia Her Lin*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

2 Citations (Scopus)

Abstract

The hydro-thermal reaction of cobalt nitrate with 4,4′-bipyridine and 3-nitro-benzoic acid lead to the formation of the title complex, [Co(C 7H4NO4)2(C10H 8N2)2] n. In the crystal structure, the Co II atoms are coordinated by two terminal carboxyl-ate anions and four 4,4′-bipyridine ligands within slightly distorted octa-hedra. The Co II atom and one of the two independent 4,4′-bipyridine ligands are located on a twofold rotation axis, while the second independent 4,4′-bipyridine mol-ecule is located on a centre of inversion. One of the two rings of one 4,4′-bipyridine ligand is disordered over two orientations and was refined using a split model [occupancy ratio 0.68 (2):0.32 (2)]. The CoII atoms are connected by the 4,4′-bipyridine ligands into layers, which are located parallel to the ab plane.

Original languageEnglish
Pages (from-to)m1302-m1303
JournalActa Crystallographica Section E: Structure Reports Online
Volume65
Issue number11
DOIs
Publication statusPublished - 2009
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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