Abstract
We study the polarization and electrostatic interactions of an ionic system under geometric confinement in the strong-interacting regime. The geometric confinement is introduced via a simple two-ring model, where ions of each species are confined on a ring, respectively. The observed polarization curve exhibits staircase transitions in the low-temperature regime, due to the crossover between energy local minima. We examine the criterion for the validity of the linear response theory and introduce a simple two-state picture that illustrates the signatures of the crossover phenomena.
Original language | English |
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Article number | 244904 |
Journal | Journal of Chemical Physics |
Volume | 137 |
Issue number | 24 |
DOIs | |
Publication status | Published - 2012 Dec 28 |
ASJC Scopus subject areas
- General Physics and Astronomy
- Physical and Theoretical Chemistry