Oxidation of Tricarbonyl (η1 η2‐but‐3‐en‐1‐yl)iron(0)and Tricarbonyl (η3‐allyl)iron(0) Anion Complexes with Dioxygen

Chong‐Chen ‐C Hwu; Ming‐Chang P. Yeh

doi:10.1002/jccs.199500112

Oxidation of Tricarbonyl (η¹ η²‐but‐3‐en‐1‐yl)iron(0)and Tricarbonyl (η³‐allyl)iron(0) Anion Complexes with Dioxygen

Chong‐Chen ‐C Hwu^*, Ming‐Chang P. Yeh

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The addition of reactive carbanions to tricarbonyl(η⁴‐1,3‐diene)iron(0) complexes proceeded at −78 °C to give putative tricarbonyl(η¹,η²‐but‐3‐en‐1‐y1)iron(0) anion complexes and at 25 °C to produce postulated tricarbonyl(η³‐allyl)iron(O) anion complexes; trapping of reactive intermediates with dioxygen produced γ,δ‐unsaturated acids and allylic alcohols, respectively.

Original language	English
Pages (from-to)	825-831
Number of pages	7
Journal	Journal of the Chinese Chemical Society
Volume	42
Issue number	5
DOIs	https://doi.org/10.1002/jccs.199500112
Publication status	Published - 1995 Oct

Keywords

Allylic alcohols
Diene iron complex
γ,δ‐Unsaturated acids

ASJC Scopus subject areas

General Chemistry

Access to Document

10.1002/jccs.199500112

Cite this

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title = "Oxidation of Tricarbonyl (η1 η2‐but‐3‐en‐1‐yl)iron(0)and Tricarbonyl (η3‐allyl)iron(0) Anion Complexes with Dioxygen",

abstract = "The addition of reactive carbanions to tricarbonyl(η4‐1,3‐diene)iron(0) complexes proceeded at −78 °C to give putative tricarbonyl(η1,η2‐but‐3‐en‐1‐y1)iron(0) anion complexes and at 25 °C to produce postulated tricarbonyl(η3‐allyl)iron(O) anion complexes; trapping of reactive intermediates with dioxygen produced γ,δ‐unsaturated acids and allylic alcohols, respectively.",

keywords = "Allylic alcohols, Diene iron complex, γ,δ‐Unsaturated acids",

author = "Hwu, {Chong‐Chen ‐C} and Yeh, {Ming‐Chang P.}",

year = "1995",

month = oct,

doi = "10.1002/jccs.199500112",

language = "English",

volume = "42",

pages = "825--831",

journal = "Journal of the Chinese Chemical Society",

issn = "0009-4536",

publisher = "Chinese Chemical Society",

number = "5",

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T1 - Oxidation of Tricarbonyl (η1 η2‐but‐3‐en‐1‐yl)iron(0)and Tricarbonyl (η3‐allyl)iron(0) Anion Complexes with Dioxygen

AU - Hwu, Chong‐Chen ‐C

AU - Yeh, Ming‐Chang P.

PY - 1995/10

Y1 - 1995/10

N2 - The addition of reactive carbanions to tricarbonyl(η4‐1,3‐diene)iron(0) complexes proceeded at −78 °C to give putative tricarbonyl(η1,η2‐but‐3‐en‐1‐y1)iron(0) anion complexes and at 25 °C to produce postulated tricarbonyl(η3‐allyl)iron(O) anion complexes; trapping of reactive intermediates with dioxygen produced γ,δ‐unsaturated acids and allylic alcohols, respectively.

AB - The addition of reactive carbanions to tricarbonyl(η4‐1,3‐diene)iron(0) complexes proceeded at −78 °C to give putative tricarbonyl(η1,η2‐but‐3‐en‐1‐y1)iron(0) anion complexes and at 25 °C to produce postulated tricarbonyl(η3‐allyl)iron(O) anion complexes; trapping of reactive intermediates with dioxygen produced γ,δ‐unsaturated acids and allylic alcohols, respectively.

KW - Allylic alcohols

KW - Diene iron complex

KW - γ,δ‐Unsaturated acids

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