Oxidation of Tricarbonyl (η1 η2‐but‐3‐en‐1‐yl)iron(0)and Tricarbonyl (η3‐allyl)iron(0) Anion Complexes with Dioxygen

Chong‐Chen ‐C Hwu, Ming‐Chang P. Yeh

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2 Citations (Scopus)

Abstract

The addition of reactive carbanions to tricarbonyl(η4‐1,3‐diene)iron(0) complexes proceeded at −78 °C to give putative tricarbonyl(η12‐but‐3‐en‐1‐y1)iron(0) anion complexes and at 25 °C to produce postulated tricarbonyl(η3‐allyl)iron(O) anion complexes; trapping of reactive intermediates with dioxygen produced γ,δ‐unsaturated acids and allylic alcohols, respectively.

Original languageEnglish
Pages (from-to)825-831
Number of pages7
JournalJournal of the Chinese Chemical Society
Volume42
Issue number5
DOIs
Publication statusPublished - 1995 Oct

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Keywords

  • Allylic alcohols
  • Diene iron complex
  • γ,δ‐Unsaturated acids

ASJC Scopus subject areas

  • Chemistry(all)

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