Oxidation of Tricarbonyl (η1 η2‐but‐3‐en‐1‐yl)iron(0)and Tricarbonyl (η3‐allyl)iron(0) Anion Complexes with Dioxygen

Chong‐Chen ‐C Hwu, Ming‐Chang P. Yeh

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

The addition of reactive carbanions to tricarbonyl(η4‐1,3‐diene)iron(0) complexes proceeded at −78 °C to give putative tricarbonyl(η12‐but‐3‐en‐1‐y1)iron(0) anion complexes and at 25 °C to produce postulated tricarbonyl(η3‐allyl)iron(O) anion complexes; trapping of reactive intermediates with dioxygen produced γ,δ‐unsaturated acids and allylic alcohols, respectively.

Original languageEnglish
Pages (from-to)825-831
Number of pages7
JournalJournal of the Chinese Chemical Society
Volume42
Issue number5
DOIs
Publication statusPublished - 1995 Oct

Fingerprint

Anions
Iron
Oxygen
Oxidation
Acids
allyl alcohol

Keywords

  • Allylic alcohols
  • Diene iron complex
  • γ,δ‐Unsaturated acids

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

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title = "Oxidation of Tricarbonyl (η1 η2‐but‐3‐en‐1‐yl)iron(0)and Tricarbonyl (η3‐allyl)iron(0) Anion Complexes with Dioxygen",
abstract = "The addition of reactive carbanions to tricarbonyl(η4‐1,3‐diene)iron(0) complexes proceeded at −78 °C to give putative tricarbonyl(η1,η2‐but‐3‐en‐1‐y1)iron(0) anion complexes and at 25 °C to produce postulated tricarbonyl(η3‐allyl)iron(O) anion complexes; trapping of reactive intermediates with dioxygen produced γ,δ‐unsaturated acids and allylic alcohols, respectively.",
keywords = "Allylic alcohols, Diene iron complex, γ,δ‐Unsaturated acids",
author = "Hwu, {Chong‐Chen ‐C} and Yeh, {Ming‐Chang P.}",
year = "1995",
month = "10",
doi = "10.1002/jccs.199500112",
language = "English",
volume = "42",
pages = "825--831",
journal = "Journal of the Chinese Chemical Society",
issn = "0009-4536",
publisher = "Chinese Chemical Society",
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TY - JOUR

T1 - Oxidation of Tricarbonyl (η1 η2‐but‐3‐en‐1‐yl)iron(0)and Tricarbonyl (η3‐allyl)iron(0) Anion Complexes with Dioxygen

AU - Hwu, Chong‐Chen ‐C

AU - Yeh, Ming‐Chang P.

PY - 1995/10

Y1 - 1995/10

N2 - The addition of reactive carbanions to tricarbonyl(η4‐1,3‐diene)iron(0) complexes proceeded at −78 °C to give putative tricarbonyl(η1,η2‐but‐3‐en‐1‐y1)iron(0) anion complexes and at 25 °C to produce postulated tricarbonyl(η3‐allyl)iron(O) anion complexes; trapping of reactive intermediates with dioxygen produced γ,δ‐unsaturated acids and allylic alcohols, respectively.

AB - The addition of reactive carbanions to tricarbonyl(η4‐1,3‐diene)iron(0) complexes proceeded at −78 °C to give putative tricarbonyl(η1,η2‐but‐3‐en‐1‐y1)iron(0) anion complexes and at 25 °C to produce postulated tricarbonyl(η3‐allyl)iron(O) anion complexes; trapping of reactive intermediates with dioxygen produced γ,δ‐unsaturated acids and allylic alcohols, respectively.

KW - Allylic alcohols

KW - Diene iron complex

KW - γ,δ‐Unsaturated acids

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DO - 10.1002/jccs.199500112

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SP - 825

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JO - Journal of the Chinese Chemical Society

JF - Journal of the Chinese Chemical Society

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