New titanium and nickel gallophosphates with layered structures

Chia Her Lin; Sue Lein Wang

doi:10.1021/ic0494556

New titanium and nickel gallophosphates with layered structures

Chia Her Lin, Sue Lein Wang^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

Two new transition-metal gallophosphates, (H₂C₄H ₁₀N₂)₃[(Ti_2.5(H₂O) ₄Ga_5.5(PO₄)₁₀]·2H ₂O (TGP-1) and [H_3.5(C₄H₁₃N ₃)₂]-[(Ni_0.5(OH)₄Ga _5.5(PO₄)₃(HPO₄)₄] ·2H₂O (NGP-1), have been synthesized under mild hydrothermal conditions and characterized by single-crystal X-ray diffraction, thermogravimetric analysis, electron paramagnetic resonance, electron probe microanalysis, and magnetic susceptibility data. TGP-1 exhibits a unique two-dimensional structure consisting of tetrahedral and octahedral metals centers and is the foremost paramagnetic TiGaPO material ever prepared. NGP-1 as well represents the first NiGaPO compound and adopts a layer structure that is constructed from hexameric M-O clusters of trigonal bipyramids and octahedra. In both compounds, the transition metals incorporate with gallium into octahedral sites only, while the four- and five-coordinated metals centers are only Ga ³⁺ ions. The unique sites for Ti³⁺ and Ni²⁺ ions have been initially elucidated from single-crystal structure refinements and further confirmed by bond-valence-sum calculations, EPR, and magnetic susceptibility studies. Crystal data: TGP-1, monoclinic, P2₁/c; a = 25.692(2) Å, b = 9.6552(8) Å c = 9.8418(8) Å, β = 96.737(2)°, V = 2424.5(3) Å³, and Z = 2; NGP-1, monoclinic, C2/c, a = 20.8363(12) Å, b = 11.9546(7) Å, c = 16.4577(9) Å, β = 117.285(1)°, V = 3643.3(1) Å³, Z = 4.

Original language	English
Pages (from-to)	251-257
Number of pages	7
Journal	Inorganic Chemistry
Volume	44
Issue number	2
DOIs	https://doi.org/10.1021/ic0494556
Publication status	Published - 2005 Jan 24
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

Access to Document

10.1021/ic0494556

Cite this

@article{d4f58dd20e01404e94d1306f84190651,

title = "New titanium and nickel gallophosphates with layered structures",

abstract = "Two new transition-metal gallophosphates, (H2C4H 10N2)3[(Ti2.5(H2O) 4Ga5.5(PO4)10]·2H 2O (TGP-1) and [H3.5(C4H13N 3)2]-[(Ni0.5(OH)4Ga 5.5(PO4)3(HPO4)4] ·2H2O (NGP-1), have been synthesized under mild hydrothermal conditions and characterized by single-crystal X-ray diffraction, thermogravimetric analysis, electron paramagnetic resonance, electron probe microanalysis, and magnetic susceptibility data. TGP-1 exhibits a unique two-dimensional structure consisting of tetrahedral and octahedral metals centers and is the foremost paramagnetic TiGaPO material ever prepared. NGP-1 as well represents the first NiGaPO compound and adopts a layer structure that is constructed from hexameric M-O clusters of trigonal bipyramids and octahedra. In both compounds, the transition metals incorporate with gallium into octahedral sites only, while the four- and five-coordinated metals centers are only Ga 3+ ions. The unique sites for Ti3+ and Ni2+ ions have been initially elucidated from single-crystal structure refinements and further confirmed by bond-valence-sum calculations, EPR, and magnetic susceptibility studies. Crystal data: TGP-1, monoclinic, P21/c; a = 25.692(2) {\AA}, b = 9.6552(8) {\AA} c = 9.8418(8) {\AA}, β = 96.737(2)°, V = 2424.5(3) {\AA}3, and Z = 2; NGP-1, monoclinic, C2/c, a = 20.8363(12) {\AA}, b = 11.9546(7) {\AA}, c = 16.4577(9) {\AA}, β = 117.285(1)°, V = 3643.3(1) {\AA}3, Z = 4.",

author = "Lin, {Chia Her} and Wang, {Sue Lein}",

year = "2005",

month = jan,

day = "24",

doi = "10.1021/ic0494556",

language = "English",

volume = "44",

pages = "251--257",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "2",

}

TY - JOUR

T1 - New titanium and nickel gallophosphates with layered structures

AU - Lin, Chia Her

AU - Wang, Sue Lein

PY - 2005/1/24

Y1 - 2005/1/24

N2 - Two new transition-metal gallophosphates, (H2C4H 10N2)3[(Ti2.5(H2O) 4Ga5.5(PO4)10]·2H 2O (TGP-1) and [H3.5(C4H13N 3)2]-[(Ni0.5(OH)4Ga 5.5(PO4)3(HPO4)4] ·2H2O (NGP-1), have been synthesized under mild hydrothermal conditions and characterized by single-crystal X-ray diffraction, thermogravimetric analysis, electron paramagnetic resonance, electron probe microanalysis, and magnetic susceptibility data. TGP-1 exhibits a unique two-dimensional structure consisting of tetrahedral and octahedral metals centers and is the foremost paramagnetic TiGaPO material ever prepared. NGP-1 as well represents the first NiGaPO compound and adopts a layer structure that is constructed from hexameric M-O clusters of trigonal bipyramids and octahedra. In both compounds, the transition metals incorporate with gallium into octahedral sites only, while the four- and five-coordinated metals centers are only Ga 3+ ions. The unique sites for Ti3+ and Ni2+ ions have been initially elucidated from single-crystal structure refinements and further confirmed by bond-valence-sum calculations, EPR, and magnetic susceptibility studies. Crystal data: TGP-1, monoclinic, P21/c; a = 25.692(2) Å, b = 9.6552(8) Å c = 9.8418(8) Å, β = 96.737(2)°, V = 2424.5(3) Å3, and Z = 2; NGP-1, monoclinic, C2/c, a = 20.8363(12) Å, b = 11.9546(7) Å, c = 16.4577(9) Å, β = 117.285(1)°, V = 3643.3(1) Å3, Z = 4.

AB - Two new transition-metal gallophosphates, (H2C4H 10N2)3[(Ti2.5(H2O) 4Ga5.5(PO4)10]·2H 2O (TGP-1) and [H3.5(C4H13N 3)2]-[(Ni0.5(OH)4Ga 5.5(PO4)3(HPO4)4] ·2H2O (NGP-1), have been synthesized under mild hydrothermal conditions and characterized by single-crystal X-ray diffraction, thermogravimetric analysis, electron paramagnetic resonance, electron probe microanalysis, and magnetic susceptibility data. TGP-1 exhibits a unique two-dimensional structure consisting of tetrahedral and octahedral metals centers and is the foremost paramagnetic TiGaPO material ever prepared. NGP-1 as well represents the first NiGaPO compound and adopts a layer structure that is constructed from hexameric M-O clusters of trigonal bipyramids and octahedra. In both compounds, the transition metals incorporate with gallium into octahedral sites only, while the four- and five-coordinated metals centers are only Ga 3+ ions. The unique sites for Ti3+ and Ni2+ ions have been initially elucidated from single-crystal structure refinements and further confirmed by bond-valence-sum calculations, EPR, and magnetic susceptibility studies. Crystal data: TGP-1, monoclinic, P21/c; a = 25.692(2) Å, b = 9.6552(8) Å c = 9.8418(8) Å, β = 96.737(2)°, V = 2424.5(3) Å3, and Z = 2; NGP-1, monoclinic, C2/c, a = 20.8363(12) Å, b = 11.9546(7) Å, c = 16.4577(9) Å, β = 117.285(1)°, V = 3643.3(1) Å3, Z = 4.

UR - http://www.scopus.com/inward/record.url?scp=12344299164&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=12344299164&partnerID=8YFLogxK

U2 - 10.1021/ic0494556

DO - 10.1021/ic0494556

M3 - Article

AN - SCOPUS:12344299164

SN - 0020-1669

VL - 44

SP - 251

EP - 257

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 2

ER -

New titanium and nickel gallophosphates with layered structures

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this