New electrically conducting materials based on the dmit ligand

A. E. Pullen; K. A. Abboud; J. R. Reynolds; J. Piotraschke; S. Zeltner; R. M. Olk; E. Hoyer; H. L. Liu; D. B. Tanner

doi:10.1016/s0379-6779(97)80906-x

New electrically conducting materials based on the dmit ligand

A. E. Pullen^*
, K. A. Abboud
, J. R. Reynolds
, J. Piotraschke
, S. Zeltner
, R. M. Olk
, E. Hoyer
, H. L. Liu
, D. B. Tanner

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

The synthesis, X-ray structure analysis and electrochemical characterization of a series of chalcogen-rich, extensively conjugated, and in some cases fully planar tetrathiooxalato bridged dmit-based bimetallic Cu(II) and Ni(II) complexes for molecular conducting materials are reported. Also reported is the synthesis and temperature-dependent electrical conductivity of the new dmit based anion radical salt complex (CH₃(C₆H₅)₃P) [Ni(dmit)₂]₃.

Original language	English
Pages (from-to)	1791-1793
Number of pages	3
Journal	Synthetic Metals
Volume	86
Issue number	1-3
DOIs	https://doi.org/10.1016/s0379-6779(97)80906-x
Publication status	Published - 1997 Feb 28
Externally published	Yes

Keywords

Conductivity
Electrocrystallization
Organic conductors
Radical anion salt
X-ray diffraction

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering
Metals and Alloys
Materials Chemistry

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10.1016/s0379-6779(97)80906-x

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@article{74a733f3799440ae96ca04a1cc6d93e2,

title = "New electrically conducting materials based on the dmit ligand",

abstract = "The synthesis, X-ray structure analysis and electrochemical characterization of a series of chalcogen-rich, extensively conjugated, and in some cases fully planar tetrathiooxalato bridged dmit-based bimetallic Cu(II) and Ni(II) complexes for molecular conducting materials are reported. Also reported is the synthesis and temperature-dependent electrical conductivity of the new dmit based anion radical salt complex (CH3(C6H5)3P) [Ni(dmit)2]3.",

keywords = "Conductivity, Electrocrystallization, Organic conductors, Radical anion salt, X-ray diffraction",

author = "Pullen, \{A. E.\} and Abboud, \{K. A.\} and Reynolds, \{J. R.\} and J. Piotraschke and S. Zeltner and Olk, \{R. M.\} and E. Hoyer and Liu, \{H. L.\} and Tanner, \{D. B.\}",

note = "Funding Information: This work was funded by grants from the Air Force Office of Scientific Research (F49620-96-l-0067 and F49620-93-l-0322), the IAESTE program at the University of Leipzig, Leipzig, Germany (ref \#951405-R) and the National Science Foundation (DMR-9403894). KAA wishes to acknowledge the National Science Foundation for funding of the purchase of the X-ray equipment.",

year = "1997",

month = feb,

day = "28",

doi = "10.1016/s0379-6779(97)80906-x",

language = "English",

volume = "86",

pages = "1791--1793",

journal = "Synthetic Metals",

issn = "0379-6779",

publisher = "Elsevier BV",

number = "1-3",

}

TY - JOUR

T1 - New electrically conducting materials based on the dmit ligand

AU - Pullen, A. E.

AU - Abboud, K. A.

AU - Reynolds, J. R.

AU - Piotraschke, J.

AU - Zeltner, S.

AU - Olk, R. M.

AU - Hoyer, E.

AU - Liu, H. L.

AU - Tanner, D. B.

N1 - Funding Information: This work was funded by grants from the Air Force Office of Scientific Research (F49620-96-l-0067 and F49620-93-l-0322), the IAESTE program at the University of Leipzig, Leipzig, Germany (ref #951405-R) and the National Science Foundation (DMR-9403894). KAA wishes to acknowledge the National Science Foundation for funding of the purchase of the X-ray equipment.

PY - 1997/2/28

Y1 - 1997/2/28

N2 - The synthesis, X-ray structure analysis and electrochemical characterization of a series of chalcogen-rich, extensively conjugated, and in some cases fully planar tetrathiooxalato bridged dmit-based bimetallic Cu(II) and Ni(II) complexes for molecular conducting materials are reported. Also reported is the synthesis and temperature-dependent electrical conductivity of the new dmit based anion radical salt complex (CH3(C6H5)3P) [Ni(dmit)2]3.

AB - The synthesis, X-ray structure analysis and electrochemical characterization of a series of chalcogen-rich, extensively conjugated, and in some cases fully planar tetrathiooxalato bridged dmit-based bimetallic Cu(II) and Ni(II) complexes for molecular conducting materials are reported. Also reported is the synthesis and temperature-dependent electrical conductivity of the new dmit based anion radical salt complex (CH3(C6H5)3P) [Ni(dmit)2]3.

KW - Conductivity

KW - Electrocrystallization

KW - Organic conductors

KW - Radical anion salt

KW - X-ray diffraction

UR - https://www.scopus.com/pages/publications/0039243902

UR - https://www.scopus.com/pages/publications/0039243902#tab=citedBy

U2 - 10.1016/s0379-6779(97)80906-x

DO - 10.1016/s0379-6779(97)80906-x

M3 - Article

AN - SCOPUS:0039243902

SN - 0379-6779

VL - 86

SP - 1791

EP - 1793

JO - Synthetic Metals

JF - Synthetic Metals

IS - 1-3

ER -

New electrically conducting materials based on the dmit ligand

Abstract

Keywords

ASJC Scopus subject areas

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