Multielectron photochemistry of quadruply bonded metal-metal complexes

Colleen M. Partigianoni; I. Jy Chang; Daniel G. Nocera

doi:10.1016/0010-8545(90)80083-6

Multielectron photochemistry of quadruply bonded metal-metal complexes

Colleen M. Partigianoni^*
, I. Jy Chang
, Daniel G. Nocera

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

The structural, electronic, and oxidation-reduction properties of multiply bonded metal-metal ({A figure is presented}) dimers presage a rich excited state chemistry for these complexes. Our work has emphasized photochemical pathways that utilize ({A figure is presented}) dimers to promote overall multielectron transformations. Multielectron photochemistry can only be achieved by correctly manipulating the molecular and electronic structures of these dimers such that one-electron pathways are circumvented. We now present a summary of the strategy used for the rational design of ({A figure is presented}) multielectron photochemical schemes.

Original language	English
Pages (from-to)	105-117
Number of pages	13
Journal	Coordination Chemistry Reviews
Volume	97
Issue number	C
DOIs	https://doi.org/10.1016/0010-8545(90)80083-6
Publication status	Published - 1990 Jan
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry

Access to Document

10.1016/0010-8545(90)80083-6

Cite this

@article{f2ed07e9809f47c7bc4e8e76cd28c80f,

title = "Multielectron photochemistry of quadruply bonded metal-metal complexes",

abstract = "The structural, electronic, and oxidation-reduction properties of multiply bonded metal-metal (\{A figure is presented\}) dimers presage a rich excited state chemistry for these complexes. Our work has emphasized photochemical pathways that utilize (\{A figure is presented\}) dimers to promote overall multielectron transformations. Multielectron photochemistry can only be achieved by correctly manipulating the molecular and electronic structures of these dimers such that one-electron pathways are circumvented. We now present a summary of the strategy used for the rational design of (\{A figure is presented\}) multielectron photochemical schemes.",

author = "Partigianoni, \{Colleen M.\} and Chang, \{I. Jy\} and Nocera, \{Daniel G.\}",

note = "Funding Information: ACKNOWLEDGEMENT This work was supported by grants from the National Science Foundation, AMAX Foundation, Research Corporation, and a Henry and Camille Dreyfus Grant for Newly Appointed Young Faculty in Chemistry. DGN also gratefully acknowledges the support provided by a Presidential Young Investigator Award, administered by the National Science Foundation. We express our gratitude to Dr. Jay Winkler for providing access to the picosecond laser facilities at Brookhaven National Laboratory.",

year = "1990",

month = jan,

doi = "10.1016/0010-8545(90)80083-6",

language = "English",

volume = "97",

pages = "105--117",

journal = "Coordination Chemistry Reviews",

issn = "0010-8545",

publisher = "Elsevier BV",

number = "C",

}

TY - JOUR

T1 - Multielectron photochemistry of quadruply bonded metal-metal complexes

AU - Partigianoni, Colleen M.

AU - Chang, I. Jy

AU - Nocera, Daniel G.

N1 - Funding Information: ACKNOWLEDGEMENT This work was supported by grants from the National Science Foundation, AMAX Foundation, Research Corporation, and a Henry and Camille Dreyfus Grant for Newly Appointed Young Faculty in Chemistry. DGN also gratefully acknowledges the support provided by a Presidential Young Investigator Award, administered by the National Science Foundation. We express our gratitude to Dr. Jay Winkler for providing access to the picosecond laser facilities at Brookhaven National Laboratory.

PY - 1990/1

Y1 - 1990/1

N2 - The structural, electronic, and oxidation-reduction properties of multiply bonded metal-metal ({A figure is presented}) dimers presage a rich excited state chemistry for these complexes. Our work has emphasized photochemical pathways that utilize ({A figure is presented}) dimers to promote overall multielectron transformations. Multielectron photochemistry can only be achieved by correctly manipulating the molecular and electronic structures of these dimers such that one-electron pathways are circumvented. We now present a summary of the strategy used for the rational design of ({A figure is presented}) multielectron photochemical schemes.

AB - The structural, electronic, and oxidation-reduction properties of multiply bonded metal-metal ({A figure is presented}) dimers presage a rich excited state chemistry for these complexes. Our work has emphasized photochemical pathways that utilize ({A figure is presented}) dimers to promote overall multielectron transformations. Multielectron photochemistry can only be achieved by correctly manipulating the molecular and electronic structures of these dimers such that one-electron pathways are circumvented. We now present a summary of the strategy used for the rational design of ({A figure is presented}) multielectron photochemical schemes.

UR - https://www.scopus.com/pages/publications/0242635027

UR - https://www.scopus.com/pages/publications/0242635027#tab=citedBy

U2 - 10.1016/0010-8545(90)80083-6

DO - 10.1016/0010-8545(90)80083-6

M3 - Article

AN - SCOPUS:0242635027

SN - 0010-8545

VL - 97

SP - 105

EP - 117

JO - Coordination Chemistry Reviews

JF - Coordination Chemistry Reviews

IS - C

ER -

Multielectron photochemistry of quadruply bonded metal-metal complexes

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this