TY - JOUR
T1 - Multielectron photochemistry of quadruply bonded metal-metal complexes
AU - Partigianoni, Colleen M.
AU - Chang, I. Jy
AU - Nocera, Daniel G.
N1 - Funding Information:
ACKNOWLEDGEMENT This work was supported by grants from the National Science Foundation, AMAX Foundation, Research Corporation, and a Henry and Camille Dreyfus Grant for Newly Appointed Young Faculty in Chemistry. DGN also gratefully acknowledges the support provided by a Presidential Young Investigator Award, administered by the National Science Foundation. We express our gratitude to Dr. Jay Winkler for providing access to the picosecond laser facilities at Brookhaven National Laboratory.
PY - 1990/1
Y1 - 1990/1
N2 - The structural, electronic, and oxidation-reduction properties of multiply bonded metal-metal ({A figure is presented}) dimers presage a rich excited state chemistry for these complexes. Our work has emphasized photochemical pathways that utilize ({A figure is presented}) dimers to promote overall multielectron transformations. Multielectron photochemistry can only be achieved by correctly manipulating the molecular and electronic structures of these dimers such that one-electron pathways are circumvented. We now present a summary of the strategy used for the rational design of ({A figure is presented}) multielectron photochemical schemes.
AB - The structural, electronic, and oxidation-reduction properties of multiply bonded metal-metal ({A figure is presented}) dimers presage a rich excited state chemistry for these complexes. Our work has emphasized photochemical pathways that utilize ({A figure is presented}) dimers to promote overall multielectron transformations. Multielectron photochemistry can only be achieved by correctly manipulating the molecular and electronic structures of these dimers such that one-electron pathways are circumvented. We now present a summary of the strategy used for the rational design of ({A figure is presented}) multielectron photochemical schemes.
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U2 - 10.1016/0010-8545(90)80083-6
DO - 10.1016/0010-8545(90)80083-6
M3 - Article
AN - SCOPUS:0242635027
VL - 97
SP - 105
EP - 117
JO - Coordination Chemistry Reviews
JF - Coordination Chemistry Reviews
SN - 0010-8545
IS - C
ER -