Multielectron photochemistry of quadruply bonded metal-metal complexes

Colleen M. Partigianoni, I. Jy Chang, Daniel G. Nocera

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

The structural, electronic, and oxidation-reduction properties of multiply bonded metal-metal ({A figure is presented}) dimers presage a rich excited state chemistry for these complexes. Our work has emphasized photochemical pathways that utilize ({A figure is presented}) dimers to promote overall multielectron transformations. Multielectron photochemistry can only be achieved by correctly manipulating the molecular and electronic structures of these dimers such that one-electron pathways are circumvented. We now present a summary of the strategy used for the rational design of ({A figure is presented}) multielectron photochemical schemes.

Original languageEnglish
Pages (from-to)105-117
Number of pages13
JournalCoordination Chemistry Reviews
Volume97
Issue numberC
DOIs
Publication statusPublished - 1990 Jan

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ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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