Abstract
The structural, electronic, and oxidation-reduction properties of multiply bonded metal-metal ({A figure is presented}) dimers presage a rich excited state chemistry for these complexes. Our work has emphasized photochemical pathways that utilize ({A figure is presented}) dimers to promote overall multielectron transformations. Multielectron photochemistry can only be achieved by correctly manipulating the molecular and electronic structures of these dimers such that one-electron pathways are circumvented. We now present a summary of the strategy used for the rational design of ({A figure is presented}) multielectron photochemical schemes.
| Original language | English |
|---|---|
| Pages (from-to) | 105-117 |
| Number of pages | 13 |
| Journal | Coordination Chemistry Reviews |
| Volume | 97 |
| Issue number | C |
| DOIs | |
| Publication status | Published - 1990 Jan |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry
- Materials Chemistry
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Partigianoni, C. M., Chang, I. J., & Nocera, D. G. (1990). Multielectron photochemistry of quadruply bonded metal-metal complexes. Coordination Chemistry Reviews, 97(C), 105-117. https://doi.org/10.1016/0010-8545(90)80083-6