Multi-dimensional cobalt(II) and nickel(II) coordination polymers

Shih Chen Hsu; Pei Shiuan Chiang; Hsin Kuan Liu; Sheng Han Lo; Chia Her Lin

doi:10.1002/jccs.201100492

Multi-dimensional cobalt(II) and nickel(II) coordination polymers

Shih Chen Hsu, Pei Shiuan Chiang, Hsin Kuan Liu, Sheng Han Lo, Chia Her Lin^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

A series of metal coordination polymers, [Co ₂(NB) ₄(bpp) ₂(H ₂O)]H ₂O (1), [Co ₂(e,e-trans-chdc)(e,a-cischdc)(bpp) ₂] (2), [Ni(e,e-trans-chdc)(bpp)(H ₂O) ₂] (3), [Ni ₂(PDA) ₂(bpp) ₂(H ₂O) ₃]·H ₂O (4), and [Ni-(mBDC)(bpp)] (5) (NB = 3-nitrobenzoate anion; bpp = 4,4'-trimethylene dipyridine; chdc = cyclohexane-1,4-dicarboxylate anion; PDA = 1,4-phenylenediacetate anion; mBDC = 1,3-benzene dicarboxylate anion), were synthesized from metal ions and organic mixed-ligands by hydrothermal reactions. The single crystal structure analysis revealed that 1, 3, and 4 were 2D sheets with bilayer (1 and 4) and 2-fold interpenetrated layers (3), 2 is a 3D binodal (4,5)-connected framework, and 5 is a 1D chains. The non-covalent interactions of H-bonds and π-π stacking caused this conformation of highly cross-linked networks. Compounds 1-5 were further characterized by thermal gravimetric analysis, powder X-ray diffraction, UV-vis, infrared, and PL spectroscopy.

Original language	English
Pages (from-to)	18-27
Number of pages	10
Journal	Journal of the Chinese Chemical Society
Volume	59
Issue number	1
DOIs	https://doi.org/10.1002/jccs.201100492
Publication status	Published - 2012 Jan
Externally published	Yes

Keywords

Coordination polymers
Crystal structures
Hydrothermal synthesis

ASJC Scopus subject areas

General Chemistry

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10.1002/jccs.201100492

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title = "Multi-dimensional cobalt(II) and nickel(II) coordination polymers",

abstract = "A series of metal coordination polymers, [Co 2(NB) 4(bpp) 2(H 2O)]H 2O (1), [Co 2(e,e-trans-chdc)(e,a-cischdc)(bpp) 2] (2), [Ni(e,e-trans-chdc)(bpp)(H 2O) 2] (3), [Ni 2(PDA) 2(bpp) 2(H 2O) 3]·H 2O (4), and [Ni-(mBDC)(bpp)] (5) (NB = 3-nitrobenzoate anion; bpp = 4,4'-trimethylene dipyridine; chdc = cyclohexane-1,4-dicarboxylate anion; PDA = 1,4-phenylenediacetate anion; mBDC = 1,3-benzene dicarboxylate anion), were synthesized from metal ions and organic mixed-ligands by hydrothermal reactions. The single crystal structure analysis revealed that 1, 3, and 4 were 2D sheets with bilayer (1 and 4) and 2-fold interpenetrated layers (3), 2 is a 3D binodal (4,5)-connected framework, and 5 is a 1D chains. The non-covalent interactions of H-bonds and π-π stacking caused this conformation of highly cross-linked networks. Compounds 1-5 were further characterized by thermal gravimetric analysis, powder X-ray diffraction, UV-vis, infrared, and PL spectroscopy.",

keywords = "Coordination polymers, Crystal structures, Hydrothermal synthesis",

author = "Hsu, {Shih Chen} and Chiang, {Pei Shiuan} and Liu, {Hsin Kuan} and Lo, {Sheng Han} and Lin, {Chia Her}",

year = "2012",

month = jan,

doi = "10.1002/jccs.201100492",

language = "English",

volume = "59",

pages = "18--27",

journal = "Journal of the Chinese Chemical Society",

issn = "0009-4536",

publisher = "Chinese Chemical Society",

number = "1",

}

TY - JOUR

T1 - Multi-dimensional cobalt(II) and nickel(II) coordination polymers

AU - Hsu, Shih Chen

AU - Chiang, Pei Shiuan

AU - Liu, Hsin Kuan

AU - Lo, Sheng Han

AU - Lin, Chia Her

PY - 2012/1

Y1 - 2012/1

N2 - A series of metal coordination polymers, [Co 2(NB) 4(bpp) 2(H 2O)]H 2O (1), [Co 2(e,e-trans-chdc)(e,a-cischdc)(bpp) 2] (2), [Ni(e,e-trans-chdc)(bpp)(H 2O) 2] (3), [Ni 2(PDA) 2(bpp) 2(H 2O) 3]·H 2O (4), and [Ni-(mBDC)(bpp)] (5) (NB = 3-nitrobenzoate anion; bpp = 4,4'-trimethylene dipyridine; chdc = cyclohexane-1,4-dicarboxylate anion; PDA = 1,4-phenylenediacetate anion; mBDC = 1,3-benzene dicarboxylate anion), were synthesized from metal ions and organic mixed-ligands by hydrothermal reactions. The single crystal structure analysis revealed that 1, 3, and 4 were 2D sheets with bilayer (1 and 4) and 2-fold interpenetrated layers (3), 2 is a 3D binodal (4,5)-connected framework, and 5 is a 1D chains. The non-covalent interactions of H-bonds and π-π stacking caused this conformation of highly cross-linked networks. Compounds 1-5 were further characterized by thermal gravimetric analysis, powder X-ray diffraction, UV-vis, infrared, and PL spectroscopy.

AB - A series of metal coordination polymers, [Co 2(NB) 4(bpp) 2(H 2O)]H 2O (1), [Co 2(e,e-trans-chdc)(e,a-cischdc)(bpp) 2] (2), [Ni(e,e-trans-chdc)(bpp)(H 2O) 2] (3), [Ni 2(PDA) 2(bpp) 2(H 2O) 3]·H 2O (4), and [Ni-(mBDC)(bpp)] (5) (NB = 3-nitrobenzoate anion; bpp = 4,4'-trimethylene dipyridine; chdc = cyclohexane-1,4-dicarboxylate anion; PDA = 1,4-phenylenediacetate anion; mBDC = 1,3-benzene dicarboxylate anion), were synthesized from metal ions and organic mixed-ligands by hydrothermal reactions. The single crystal structure analysis revealed that 1, 3, and 4 were 2D sheets with bilayer (1 and 4) and 2-fold interpenetrated layers (3), 2 is a 3D binodal (4,5)-connected framework, and 5 is a 1D chains. The non-covalent interactions of H-bonds and π-π stacking caused this conformation of highly cross-linked networks. Compounds 1-5 were further characterized by thermal gravimetric analysis, powder X-ray diffraction, UV-vis, infrared, and PL spectroscopy.

KW - Coordination polymers

KW - Crystal structures

KW - Hydrothermal synthesis

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JO - Journal of the Chinese Chemical Society

JF - Journal of the Chinese Chemical Society

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Multi-dimensional cobalt(II) and nickel(II) coordination polymers

Abstract

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